Synthesis of hierarchical zeolites using an inexpensive mono-quaternary ammonium surfactant as mesoporogen

X. Zhu; Roderigh Rohling; G. Filonenko; B. Mezari; J.P. Hofmann; S. Asahina; E.J.M. Hensen

doi:10.1039/C4CC06267A

Synthesis of hierarchical zeolites using an inexpensive mono-quaternary ammonium surfactant as mesoporogen

X. Zhu, Roderigh Rohling, G. Filonenko, B. Mezari, J.P. Hofmann, S. Asahina, E.J.M. Hensen

Inorganic Materials & Catalysis

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Abstract

A simple amphiphilic surfactant containing a mono-quaternary ammonium head group (N-methylpiperidine) is effective in imparting substantial mesoporosity during synthesis of SSZ-13 and ZSM-5 zeolites. Highly mesoporous SSZ-13 prepared in this manner shows greatly improved catalytic performance in the methanol-to-olefins reaction compared to bulk SSZ-13.

Original language	English
Pages (from-to)	14658-14661
Number of pages	4
Journal	Chemical Communications, ChemComm
Volume	50
Issue number	93
DOIs	https://doi.org/10.1039/C4CC06267A
Publication status	Published - 2014

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title = "Synthesis of hierarchical zeolites using an inexpensive mono-quaternary ammonium surfactant as mesoporogen",

abstract = "A simple amphiphilic surfactant containing a mono-quaternary ammonium head group (N-methylpiperidine) is effective in imparting substantial mesoporosity during synthesis of SSZ-13 and ZSM-5 zeolites. Highly mesoporous SSZ-13 prepared in this manner shows greatly improved catalytic performance in the methanol-to-olefins reaction compared to bulk SSZ-13.",

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AU - Zhu, X.

AU - Rohling, Roderigh

AU - Filonenko, G.

AU - Mezari, B.

AU - Hofmann, J.P.

AU - Asahina, S.

AU - Hensen, E.J.M.

PY - 2014

Y1 - 2014

N2 - A simple amphiphilic surfactant containing a mono-quaternary ammonium head group (N-methylpiperidine) is effective in imparting substantial mesoporosity during synthesis of SSZ-13 and ZSM-5 zeolites. Highly mesoporous SSZ-13 prepared in this manner shows greatly improved catalytic performance in the methanol-to-olefins reaction compared to bulk SSZ-13.

AB - A simple amphiphilic surfactant containing a mono-quaternary ammonium head group (N-methylpiperidine) is effective in imparting substantial mesoporosity during synthesis of SSZ-13 and ZSM-5 zeolites. Highly mesoporous SSZ-13 prepared in this manner shows greatly improved catalytic performance in the methanol-to-olefins reaction compared to bulk SSZ-13.

U2 - 10.1039/C4CC06267A

DO - 10.1039/C4CC06267A

M3 - Article

SN - 1359-7345

VL - 50

SP - 14658

EP - 14661

JO - Chemical Communications, ChemComm

JF - Chemical Communications, ChemComm

IS - 93

ER -

Synthesis of hierarchical zeolites using an inexpensive mono-quaternary ammonium surfactant as mesoporogen

Abstract

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