Synthesis of 2,2'-bipyridines : from versatile building blocks to sexy architectures and functional (nano)materials

G.R. Newkome, A.K. Patri, E. Holder, U.S. Schubert

Research output: Contribution to journalArticleAcademicpeer-review

178 Citations (Scopus)

Abstract

The latest synthetic strategies to prepare 2,2-bipyridine and its mono-substituted, symmetrical and unsymmetrical 3,3-, 4,4-, 5,5-, and 6,6-disubstituted derivatives are critically discussed and evaluated. Different coupling procedures to achieve new symmetrical and unsymmetrical functionalized 2,2-bipyridines, such as Stille-type, Negishi-type, and Suzuki-type cross-coupling reactions are discussed in detail. Moreover, condensation procedures that allow further variations are presented. The application of functional group transformations for access to additional groups is examined.
Original languageEnglish
Pages (from-to)235-254
JournalEuropean Journal of Organic Chemistry
Volume2004
Issue number2
DOIs
Publication statusPublished - 2004

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2,2'-Dipyridyl
Functional groups
Condensation
Derivatives
cross coupling
synthesis
condensation

Cite this

Newkome, G.R. ; Patri, A.K. ; Holder, E. ; Schubert, U.S. / Synthesis of 2,2'-bipyridines : from versatile building blocks to sexy architectures and functional (nano)materials. In: European Journal of Organic Chemistry. 2004 ; Vol. 2004, No. 2. pp. 235-254.
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Synthesis of 2,2'-bipyridines : from versatile building blocks to sexy architectures and functional (nano)materials. / Newkome, G.R.; Patri, A.K.; Holder, E.; Schubert, U.S.

In: European Journal of Organic Chemistry, Vol. 2004, No. 2, 2004, p. 235-254.

Research output: Contribution to journalArticleAcademicpeer-review

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AU - Schubert, U.S.

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AB - The latest synthetic strategies to prepare 2,2-bipyridine and its mono-substituted, symmetrical and unsymmetrical 3,3-, 4,4-, 5,5-, and 6,6-disubstituted derivatives are critically discussed and evaluated. Different coupling procedures to achieve new symmetrical and unsymmetrical functionalized 2,2-bipyridines, such as Stille-type, Negishi-type, and Suzuki-type cross-coupling reactions are discussed in detail. Moreover, condensation procedures that allow further variations are presented. The application of functional group transformations for access to additional groups is examined.

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M3 - Article

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JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

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