Synthesis and optical properties of (a)chiral terpyridine-ruthenium complexes

H. Hofmeier, A. El-Ghayoury, A.P.H.J. Schenning, U.S. Schubert

Research output: Contribution to journalArticleAcademicpeer-review

6 Citations (Scopus)

Abstract

Chiral terpyridine ligands have been synthesized and characterized. By applying Ru(III)/Ru(II) chem., sym. as well as asym. bis-terpyridine ruthenium(II) complexes were obtained. These materials were fully characterized and their optical properties investigated. While the chiral metal complexes revealed no Cotton effect in good solvents such as chloroform, CD-measurements in dodecane showed an effect in both ligand and MLCT regions, suggesting chirality transfer from the lateral alkyl chains to the complex core. This behavior points to the formation of supramol. aggregates in dodecane. Furthermore, the analogous achiral ligand and its corresponding ruthenium(II) complexes were prepd
Original languageEnglish
Pages (from-to)6121-6128
JournalTetrahedron
Volume60
Issue number29
DOIs
Publication statusPublished - 2004

Fingerprint

Dive into the research topics of 'Synthesis and optical properties of (a)chiral terpyridine-ruthenium complexes'. Together they form a unique fingerprint.

Cite this