Synthesis and characterization of some heterometal-substituted ammonium gallophosphates

A.R. Overweg; J.W. Haan, de; P.C.M.M. Magusin; R.A. Santen, van; G. Sankar; J.M. Thomas

doi:10.1021/cm9806331

Synthesis and characterization of some heterometal-substituted ammonium gallophosphates

A.R. Overweg
, J.W. Haan, de
, P.C.M.M. Magusin
, R.A. Santen, van
, G. Sankar
, J.M. Thomas

Research output: Contribution to journal › Article › Academic › peer-review

19 Citations (Scopus)

Abstract

Various metal-substituted ammonium gallophosphates (metal is Zn, Mn, Mg, and Fe) have been synthesized. Characterization by X-ray diffraction (XRD), X-ray absorption spectroscopy (XAS), and P-31 MAS and Ga-71 MAS NMR shows that the structures are similar and isostructural to:the known ammonium cobalt gallophosphate hydrate, [NH4][CoGa2P3O12(H2O)(2)]. It is concluded from a combined in situ XRD/XAS study that the gallophosphate molecular sieves described here are not thermally stable and lose their microporous nature above 350 degrees C

Original language	English
Pages (from-to)	1680-1686
Number of pages	7
Journal	Chemistry of Materials
Volume	11
Issue number	7
DOIs	https://doi.org/10.1021/cm9806331
Publication status	Published - 1999

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title = "Synthesis and characterization of some heterometal-substituted ammonium gallophosphates",

abstract = "Various metal-substituted ammonium gallophosphates (metal is Zn, Mn, Mg, and Fe) have been synthesized. Characterization by X-ray diffraction (XRD), X-ray absorption spectroscopy (XAS), and P-31 MAS and Ga-71 MAS NMR shows that the structures are similar and isostructural to:the known ammonium cobalt gallophosphate hydrate, [NH4][CoGa2P3O12(H2O)(2)]. It is concluded from a combined in situ XRD/XAS study that the gallophosphate molecular sieves described here are not thermally stable and lose their microporous nature above 350 degrees C",

author = "A.R. Overweg and \{Haan, de\}, J.W. and P.C.M.M. Magusin and \{Santen, van\}, R.A. and G. Sankar and J.M. Thomas",

year = "1999",

doi = "10.1021/cm9806331",

language = "English",

volume = "11",

pages = "1680--1686",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Synthesis and characterization of some heterometal-substituted ammonium gallophosphates

AU - Overweg, A.R.

AU - Haan, de, J.W.

AU - Magusin, P.C.M.M.

AU - Santen, van, R.A.

AU - Sankar, G.

AU - Thomas, J.M.

PY - 1999

Y1 - 1999

N2 - Various metal-substituted ammonium gallophosphates (metal is Zn, Mn, Mg, and Fe) have been synthesized. Characterization by X-ray diffraction (XRD), X-ray absorption spectroscopy (XAS), and P-31 MAS and Ga-71 MAS NMR shows that the structures are similar and isostructural to:the known ammonium cobalt gallophosphate hydrate, [NH4][CoGa2P3O12(H2O)(2)]. It is concluded from a combined in situ XRD/XAS study that the gallophosphate molecular sieves described here are not thermally stable and lose their microporous nature above 350 degrees C

AB - Various metal-substituted ammonium gallophosphates (metal is Zn, Mn, Mg, and Fe) have been synthesized. Characterization by X-ray diffraction (XRD), X-ray absorption spectroscopy (XAS), and P-31 MAS and Ga-71 MAS NMR shows that the structures are similar and isostructural to:the known ammonium cobalt gallophosphate hydrate, [NH4][CoGa2P3O12(H2O)(2)]. It is concluded from a combined in situ XRD/XAS study that the gallophosphate molecular sieves described here are not thermally stable and lose their microporous nature above 350 degrees C

U2 - 10.1021/cm9806331

DO - 10.1021/cm9806331

M3 - Article

SN - 0897-4756

VL - 11

SP - 1680

EP - 1686

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 7

ER -

Synthesis and characterization of some heterometal-substituted ammonium gallophosphates

Abstract

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