Synthesis and characterization of a series of diverse poly(2-oxazoline)s

K. Kempe, M. Lobert, R. Hoogenboom, U.S. Schubert

Research output: Contribution to journalArticleAcademicpeer-review

54 Citations (Scopus)

Abstract

This article describes the synthesis and characterization of a variety of new poly(2-oxazoline)s. With regard to functional polymers, 2-oxazolines represent an interesting class of monomers because of the easy variation of the substituent in 2-position. Starting from the corresponding nitriles, different 2-oxazolines were obtained containing a diverse set of 2-substituents, including thioether bonds (M11), trifiuoromethyl groups (M8, M10), and alkyl- or aryl groups (M1-M7). The subsequent polymerization of the majority of these monomers proceeded in a living manner, which was demonstrated by linear first-order kinetics, a linear increase of molar mass with conversion, and relatively narrow molar mass distributions. In addition, selected thermal and surface properties of the polymers were studied utilizing DSC and contact-angle measurements to determine the effects of different 2-substituents on the macroscopic properties. © 2009 Wiley Periodicals, Inc.
Original languageEnglish
Pages (from-to)3829-3838
JournalJournal of Polymer Science, Part A: Polymer Chemistry
Volume47
Issue number15
DOIs
Publication statusPublished - 2009

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