Synthesis and catalytic properties of pillared nickel substituted mica montmorillonite clays

J. Gaaf, R.A. Santen, van, A. Knoester, B. Wingerden, van

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Abstract

Intercalation of a Ni-substituted mica montmorillonite clay (I) with Al and Al-Si oligomers gave pillared clays (II) and (III), resp. The surface area of II is greater than I, which is greater than III, and the rates of hydroisomerization of pentane at 250 Deg catalyzed by I-III are 2.5, 3.6, and 0.3 g/g/h, resp. II and III show agglomeration of the particles, which led to suppression of hydroisomerization catalysis
Original languageEnglish
Pages (from-to)655-657
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number12
DOIs
Publication statusPublished - 1983
Externally publishedYes

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