Synthesis and self-assembly of photopolymerizable quarterthiophenes

Margarita Garcia; E.W. Meijer; Albertus Schenning

doi:10.1557/PROC-0937-M02-05

Synthesis and self-assembly of photopolymerizable quarterthiophenes

Margarita Garcia, E.W. Meijer, Albertus Schenning

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

Abstract

A variety of α,α'-subtituted quaterthiophenes containing ester, amide and polymerizable side chains have been synthesized and fully characterized. The self-assembly properties of these oligothiophenes were studied as function of the side chain. Introduction of amide functionalities highly promotes the self-assembly via n-stacking and hydrogen bond interactions, while the lack of amides prevent aggregate formation. Initial experiments show that by introducing a sorbyl moiety as a polymerizable group it is possible to achieve covalent fixation of the oligothiophene units in the self-assembled state.

Original language	English
Title of host publication	Conjugated Organic Materials
Subtitle of host publication	Synthesis, Structure, Device, and Applications
Editors	A.B. Chwang
Place of Publication	Pittsburgh
Publisher	Materials Research Society
Number of pages	11
ISBN (Print)	1558998942, 9781558998940
DOIs	https://doi.org/10.1557/PROC-0937-M02-05
Publication status	Published - 1 Dec 2006
Event	2006 MRS Spring Meeting & Exhibit - San Francisco, United States Duration: 17 Apr 2006 → 21 Apr 2006 https://www.mrs.org/spring2006 http://www.mrs.org/s06-program-a/ http://www.mrs.org/s06-program-q/

Publication series

Name	Materials Research Society Symposium Proceedings
Volume	937
ISSN (Print)	0272-9172

Conference

Conference	2006 MRS Spring Meeting & Exhibit
Country/Territory	United States
City	San Francisco
Period	17/04/06 → 21/04/06
Other	Symposium held at the 2006 MRS Spring Meeting
Internet address	https://www.mrs.org/spring2006 http://www.mrs.org/s06-program-a/ http://www.mrs.org/s06-program-q/

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Garcia, M., Meijer, E. W., & Schenning, A. (2006). Synthesis and self-assembly of photopolymerizable quarterthiophenes. In A. B. Chwang (Ed.), Conjugated Organic Materials: Synthesis, Structure, Device, and Applications Article 0937-M02-05 (Materials Research Society Symposium Proceedings; Vol. 937). Materials Research Society. https://doi.org/10.1557/PROC-0937-M02-05

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abstract = "A variety of α,α'-subtituted quaterthiophenes containing ester, amide and polymerizable side chains have been synthesized and fully characterized. The self-assembly properties of these oligothiophenes were studied as function of the side chain. Introduction of amide functionalities highly promotes the self-assembly via n-stacking and hydrogen bond interactions, while the lack of amides prevent aggregate formation. Initial experiments show that by introducing a sorbyl moiety as a polymerizable group it is possible to achieve covalent fixation of the oligothiophene units in the self-assembled state.",

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note = "2006 MRS Spring Meeting & Exhibit ; Conference date: 17-04-2006 Through 21-04-2006",

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Garcia, M, Meijer, EW & Schenning, A 2006, Synthesis and self-assembly of photopolymerizable quarterthiophenes. in AB Chwang (ed.), Conjugated Organic Materials: Synthesis, Structure, Device, and Applications., 0937-M02-05, Materials Research Society Symposium Proceedings, vol. 937, Materials Research Society, Pittsburgh, 2006 MRS Spring Meeting & Exhibit, San Francisco, California, United States, 17/04/06. https://doi.org/10.1557/PROC-0937-M02-05

Synthesis and self-assembly of photopolymerizable quarterthiophenes. / Garcia, Margarita; Meijer, E.W.; Schenning, Albertus.
Conjugated Organic Materials: Synthesis, Structure, Device, and Applications. ed. / A.B. Chwang. Pittsburgh: Materials Research Society, 2006. 0937-M02-05 (Materials Research Society Symposium Proceedings; Vol. 937).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

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N2 - A variety of α,α'-subtituted quaterthiophenes containing ester, amide and polymerizable side chains have been synthesized and fully characterized. The self-assembly properties of these oligothiophenes were studied as function of the side chain. Introduction of amide functionalities highly promotes the self-assembly via n-stacking and hydrogen bond interactions, while the lack of amides prevent aggregate formation. Initial experiments show that by introducing a sorbyl moiety as a polymerizable group it is possible to achieve covalent fixation of the oligothiophene units in the self-assembled state.

AB - A variety of α,α'-subtituted quaterthiophenes containing ester, amide and polymerizable side chains have been synthesized and fully characterized. The self-assembly properties of these oligothiophenes were studied as function of the side chain. Introduction of amide functionalities highly promotes the self-assembly via n-stacking and hydrogen bond interactions, while the lack of amides prevent aggregate formation. Initial experiments show that by introducing a sorbyl moiety as a polymerizable group it is possible to achieve covalent fixation of the oligothiophene units in the self-assembled state.

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ER -

Synthesis and self-assembly of photopolymerizable quarterthiophenes

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