Surface reactions of ethylene with deuterium, oxygen and nitrogen oxide on rhodium : kinetics and mechanism

J.W. Niemantsverdriet; H.J. Borg; R.M. van Hardeveld; R.A. Santen, van

doi:10.1002/recl.19961151107

Surface reactions of ethylene with deuterium, oxygen and nitrogen oxide on rhodium : kinetics and mechanism

J.W. Niemantsverdriet, H.J. Borg, R.M. van Hardeveld, R.A. Santen, van

Inorganic Materials & Catalysis

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Abstract

The kinetics of surface reactions of ethylene adsorbed on the (111) surface of a rhodium single crystal has been investigated by means of temperature-programmed desorption and static secondary-ion mass spectrometry (SSIMS). These reactions include the decomposition of ethylene to ethylidyne (=CCH3), and the exchange of H for D-atoms in the latter, the oxidation of adsorbed ethylene and its reaction with coadsorbed NO. The formation of relatively large amounts of HCN indicates that C-N coupling on rhodium is possible under mild conditions

Original language	English
Pages (from-to)	486-491
Journal	Recueil des Travaux Chimiques des Pays-Bas
Volume	115
Issue number	11-12
DOIs	https://doi.org/10.1002/recl.19961151107
Publication status	Published - 1996

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title = "Surface reactions of ethylene with deuterium, oxygen and nitrogen oxide on rhodium : kinetics and mechanism",

abstract = "The kinetics of surface reactions of ethylene adsorbed on the (111) surface of a rhodium single crystal has been investigated by means of temperature-programmed desorption and static secondary-ion mass spectrometry (SSIMS). These reactions include the decomposition of ethylene to ethylidyne (=CCH3), and the exchange of H for D-atoms in the latter, the oxidation of adsorbed ethylene and its reaction with coadsorbed NO. The formation of relatively large amounts of HCN indicates that C-N coupling on rhodium is possible under mild conditions",

author = "J.W. Niemantsverdriet and H.J. Borg and {van Hardeveld}, R.M. and {Santen, van}, R.A.",

year = "1996",

doi = "10.1002/recl.19961151107",

language = "English",

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pages = "486--491",

journal = "Recueil des Travaux Chimiques des Pays-Bas",

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T1 - Surface reactions of ethylene with deuterium, oxygen and nitrogen oxide on rhodium : kinetics and mechanism

AU - Niemantsverdriet, J.W.

AU - Borg, H.J.

AU - van Hardeveld, R.M.

AU - Santen, van, R.A.

PY - 1996

Y1 - 1996

N2 - The kinetics of surface reactions of ethylene adsorbed on the (111) surface of a rhodium single crystal has been investigated by means of temperature-programmed desorption and static secondary-ion mass spectrometry (SSIMS). These reactions include the decomposition of ethylene to ethylidyne (=CCH3), and the exchange of H for D-atoms in the latter, the oxidation of adsorbed ethylene and its reaction with coadsorbed NO. The formation of relatively large amounts of HCN indicates that C-N coupling on rhodium is possible under mild conditions

AB - The kinetics of surface reactions of ethylene adsorbed on the (111) surface of a rhodium single crystal has been investigated by means of temperature-programmed desorption and static secondary-ion mass spectrometry (SSIMS). These reactions include the decomposition of ethylene to ethylidyne (=CCH3), and the exchange of H for D-atoms in the latter, the oxidation of adsorbed ethylene and its reaction with coadsorbed NO. The formation of relatively large amounts of HCN indicates that C-N coupling on rhodium is possible under mild conditions

U2 - 10.1002/recl.19961151107

DO - 10.1002/recl.19961151107

M3 - Article

SN - 0165-0513

VL - 115

SP - 486

EP - 491

JO - Recueil des Travaux Chimiques des Pays-Bas

JF - Recueil des Travaux Chimiques des Pays-Bas

IS - 11-12

ER -

Surface reactions of ethylene with deuterium, oxygen and nitrogen oxide on rhodium : kinetics and mechanism

Abstract

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