Surface micellization of poly(2-oxazoline)s based copolymers containing a crystallizable block

C.A. Fustin; N. Lefevre; R. Hoogenboom; U.S. Schubert; J.M.W. Gohy

doi:10.1016/j.jcis.2008.12.026

Surface micellization of poly(2-oxazoline)s based copolymers containing a crystallizable block

C.A. Fustin, N. Lefevre, R. Hoogenboom, U.S. Schubert, J.M.W. Gohy

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

6 Citations (Scopus)

Abstract

The micellization on surfaces of copoly(2-oxazoline) diblock copolymers consisting of a crystallizable poly(2-nonyl-2-oxazoline) (pNonOx) block linked to a poly(2-ethyl-2-oxazoline) (pEtOx) block is studied. Those micelles are not pre-existing in the initial ethanol soln. but are formed during the spin-coating process by the evapn. of the solvent inducing the pptn. of the less sol. pNonOx block. The morphol. and size of the surface micelles vary according to the pNonOx molar fraction in the copolymers. Reorganization of the micelles and evolution of the surface energies after a thermal annealing are also studied. [on SciFinder (R)]

Original language	English
Pages (from-to)	91-95
Journal	Journal of Colloid and Interface Science
Volume	332
Issue number	1
DOIs	https://doi.org/10.1016/j.jcis.2008.12.026
Publication status	Published - 2009

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10.1016/j.jcis.2008.12.026

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title = "Surface micellization of poly(2-oxazoline)s based copolymers containing a crystallizable block",

abstract = "The micellization on surfaces of copoly(2-oxazoline) diblock copolymers consisting of a crystallizable poly(2-nonyl-2-oxazoline) (pNonOx) block linked to a poly(2-ethyl-2-oxazoline) (pEtOx) block is studied. Those micelles are not pre-existing in the initial ethanol soln. but are formed during the spin-coating process by the evapn. of the solvent inducing the pptn. of the less sol. pNonOx block. The morphol. and size of the surface micelles vary according to the pNonOx molar fraction in the copolymers. Reorganization of the micelles and evolution of the surface energies after a thermal annealing are also studied. [on SciFinder (R)]",

author = "C.A. Fustin and N. Lefevre and R. Hoogenboom and U.S. Schubert and J.M.W. Gohy",

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T1 - Surface micellization of poly(2-oxazoline)s based copolymers containing a crystallizable block

AU - Fustin, C.A.

AU - Lefevre, N.

AU - Hoogenboom, R.

AU - Schubert, U.S.

AU - Gohy, J.M.W.

PY - 2009

Y1 - 2009

N2 - The micellization on surfaces of copoly(2-oxazoline) diblock copolymers consisting of a crystallizable poly(2-nonyl-2-oxazoline) (pNonOx) block linked to a poly(2-ethyl-2-oxazoline) (pEtOx) block is studied. Those micelles are not pre-existing in the initial ethanol soln. but are formed during the spin-coating process by the evapn. of the solvent inducing the pptn. of the less sol. pNonOx block. The morphol. and size of the surface micelles vary according to the pNonOx molar fraction in the copolymers. Reorganization of the micelles and evolution of the surface energies after a thermal annealing are also studied. [on SciFinder (R)]

AB - The micellization on surfaces of copoly(2-oxazoline) diblock copolymers consisting of a crystallizable poly(2-nonyl-2-oxazoline) (pNonOx) block linked to a poly(2-ethyl-2-oxazoline) (pEtOx) block is studied. Those micelles are not pre-existing in the initial ethanol soln. but are formed during the spin-coating process by the evapn. of the solvent inducing the pptn. of the less sol. pNonOx block. The morphol. and size of the surface micelles vary according to the pNonOx molar fraction in the copolymers. Reorganization of the micelles and evolution of the surface energies after a thermal annealing are also studied. [on SciFinder (R)]

U2 - 10.1016/j.jcis.2008.12.026

DO - 10.1016/j.jcis.2008.12.026

M3 - Article

C2 - 19128808

SN - 0021-9797

VL - 332

SP - 91

EP - 95

JO - Journal of Colloid and Interface Science

JF - Journal of Colloid and Interface Science

IS - 1

ER -

Surface micellization of poly(2-oxazoline)s based copolymers containing a crystallizable block

Abstract

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