Supramolecular chemistry at the liquid/solid interface : a scanning tunneling microscopy approach

S. Feyter, de, A. Miura, H. Uji-i, P. Jonkheijm, A.P.H.J. Schenning, E.W. Meijer, Z. Chen, F. Würthner, N. Schuurmans, J. Esch, van, B.L. Feringa, F.C. Schryver, de

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Abstract

With scanning tunneling microscopy (STM), the intramol. conformational and intermol. ordering aspects have been investigated of a variety of org. mols. physisorbed at the liq.-solid interface. By balancing the interplay between intramol. and intermol. interactions (hydrogen bonding), leading to control of the mol. conformation, foldamers were created which order into well-defined two-dimensional crystals. The nature of the hydrogen bonding groups in conjugated oligomers leads to the formation of infinite stacks and cyclic multimers, expressing the chiral nature of the mols.
Original languageEnglish
Pages (from-to)369-372
JournalDiffusion and Defect Data. Part B, Solid State Phenomena
Volume121-123
Publication statusPublished - 2007

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