Sulphur participation in cyclization reactions

W.A.J. Loos, de, A.J.W. Kuijk, van, H.M. Iersel, van, J.W. Haan, de, H.M. Buck

Research output: Contribution to journalArticleAcademicpeer-review

4 Citations (Scopus)
78 Downloads (Pure)

Abstract

Cyclization initiated by thiiranimn ions was investigated. Cis-fused decalins were formed by a process involving inversion. In nitromethane a sulphonimn salt 8 was formed. The reactions of 8 with nucleophilic reagent deviated from those of comparable compounds. It is expected that a productcontrolled transition state accounts for this feature.
Original languageEnglish
Pages (from-to)53-57
JournalRecueil des Travaux Chimiques des Pays-Bas
Volume99
Issue number2
DOIs
Publication statusPublished - 1980

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