Sulphur and viscosity reductions in heavy hydrocarbons by subcritical water processing

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Abstract

Viscosity and sulphur content are two important properties of heavy hydrocarbons for downstream processing. Both properties can be significantly reduced in value by processing in subcritical water. Subcritical water has advantages over steam recovery methods in terms of viscosity and sulphur reduction as well as energy consumption. In order to understand the mechanism of subcritical water treatment, the chemical structure of pre- and post-processed heavy hydrocarbons are compared to each other. For subcritical water processing, viscosity reduction coincides with a reduction in average molecular weight, average carbon chain length between branching points, and sulphur content, along with an increase in volatility and H2S production. This suggests that not only are C–C bonds cracked, but also C–S-(C) bonds. Subsequent comparison of subcritical water results with those obtained for pyrolysis treatment shows that the former is faster and more effective.

LanguageEnglish
Pages1069-1076
JournalJournal of Petroleum Science and Engineering
Volume172
DOIs
StatePublished - 2019

Fingerprint

viscosity
Sulfur
Hydrocarbons
sulfur
Viscosity
hydrocarbon
Processing
Water
water
recovery method
Water treatment
Chain length
pyrolysis
water treatment
Pyrolysis
Steam
Energy utilization
Molecular weight
Recovery
Carbon

Keywords

  • Enhanced cracking
  • Subcritical water
  • Sulphur
  • Viscosity

Cite this

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title = "Sulphur and viscosity reductions in heavy hydrocarbons by subcritical water processing",
abstract = "Viscosity and sulphur content are two important properties of heavy hydrocarbons for downstream processing. Both properties can be significantly reduced in value by processing in subcritical water. Subcritical water has advantages over steam recovery methods in terms of viscosity and sulphur reduction as well as energy consumption. In order to understand the mechanism of subcritical water treatment, the chemical structure of pre- and post-processed heavy hydrocarbons are compared to each other. For subcritical water processing, viscosity reduction coincides with a reduction in average molecular weight, average carbon chain length between branching points, and sulphur content, along with an increase in volatility and H2S production. This suggests that not only are C–C bonds cracked, but also C–S-(C) bonds. Subsequent comparison of subcritical water results with those obtained for pyrolysis treatment shows that the former is faster and more effective.",
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AU - Cuijpers,M.C.M.

AU - Boot,M.D.

AU - Deen,N.G.

AU - Golombok,M.

PY - 2019

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AB - Viscosity and sulphur content are two important properties of heavy hydrocarbons for downstream processing. Both properties can be significantly reduced in value by processing in subcritical water. Subcritical water has advantages over steam recovery methods in terms of viscosity and sulphur reduction as well as energy consumption. In order to understand the mechanism of subcritical water treatment, the chemical structure of pre- and post-processed heavy hydrocarbons are compared to each other. For subcritical water processing, viscosity reduction coincides with a reduction in average molecular weight, average carbon chain length between branching points, and sulphur content, along with an increase in volatility and H2S production. This suggests that not only are C–C bonds cracked, but also C–S-(C) bonds. Subsequent comparison of subcritical water results with those obtained for pyrolysis treatment shows that the former is faster and more effective.

KW - Enhanced cracking

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KW - Sulphur

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