Substituted polycycloalkylidenepolycycloalkanes and the corresponding epidioxy compounds

J.C. Hummelen; E.W. Meijer; H. Wynberg

Substituted polycycloalkylidenepolycycloalkanes and the corresponding epidioxy compounds

J.C. Hummelen (Inventor), E.W. Meijer (Inventor), H. Wynberg (Inventor)

Research output: Patent › Patent publication

Abstract

Polycycloalkylidenepolycycloalkanes were halogenated using N-halosuccinimide, tert-Bu hypohalite, or sodium hypohalite-AcOH, and optionally substituted. Thus adamantylideneadamantane (I, R = H) was treated with N-bromosuccinimide to give I (R = Br) (II) which was treated with HOAc to give I (R = OAc). II underwent photooxygenation to give the epidioxyadamantyladamantane III. Epidioxyadamantyladamantes may be used as thermochemiluminescent labels in biol. processes and immunoassays (no data). [on SciFinder (R)]

Original language	English
Patent number	WO8303604 A1
Publication status	Published - 27 Oct 1983

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title = "Substituted polycycloalkylidenepolycycloalkanes and the corresponding epidioxy compounds",

abstract = "Polycycloalkylidenepolycycloalkanes were halogenated using N-halosuccinimide, tert-Bu hypohalite, or sodium hypohalite-AcOH, and optionally substituted. Thus adamantylideneadamantane (I, R = H) was treated with N-bromosuccinimide to give I (R = Br) (II) which was treated with HOAc to give I (R = OAc). II underwent photooxygenation to give the epidioxyadamantyladamantane III. Epidioxyadamantyladamantes may be used as thermochemiluminescent labels in biol. processes and immunoassays (no data). [on SciFinder (R)]",

author = "J.C. Hummelen and E.W. Meijer and H. Wynberg",

year = "1983",

month = oct,

day = "27",

language = "English",

type = "Patent",

note = "WO8303604 A1",

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TY - PAT

T1 - Substituted polycycloalkylidenepolycycloalkanes and the corresponding epidioxy compounds

AU - Hummelen, J.C.

AU - Meijer, E.W.

AU - Wynberg, H.

PY - 1983/10/27

Y1 - 1983/10/27

N2 - Polycycloalkylidenepolycycloalkanes were halogenated using N-halosuccinimide, tert-Bu hypohalite, or sodium hypohalite-AcOH, and optionally substituted. Thus adamantylideneadamantane (I, R = H) was treated with N-bromosuccinimide to give I (R = Br) (II) which was treated with HOAc to give I (R = OAc). II underwent photooxygenation to give the epidioxyadamantyladamantane III. Epidioxyadamantyladamantes may be used as thermochemiluminescent labels in biol. processes and immunoassays (no data). [on SciFinder (R)]

AB - Polycycloalkylidenepolycycloalkanes were halogenated using N-halosuccinimide, tert-Bu hypohalite, or sodium hypohalite-AcOH, and optionally substituted. Thus adamantylideneadamantane (I, R = H) was treated with N-bromosuccinimide to give I (R = Br) (II) which was treated with HOAc to give I (R = OAc). II underwent photooxygenation to give the epidioxyadamantyladamantane III. Epidioxyadamantyladamantes may be used as thermochemiluminescent labels in biol. processes and immunoassays (no data). [on SciFinder (R)]

UR - http://preview.espacenet.com/origdoc?DB=EPODOC&IDX=US4705847&F=0&RPN=WO8303604&DOC=deb45b02a96822d9935007c28a42e9b960

M3 - Patent publication

M1 - WO8303604 A1

ER -

Substituted polycycloalkylidenepolycycloalkanes and the corresponding epidioxy compounds

Abstract

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