Studies of solvated electrons in LiBr + HMPA solutions using the rotating ring-disk electrode technique. Part 2. The reaction of benzene with solvated electrons

P.J.M. Andel-Scheffer, van; A.H. Wonders; E. Barendrecht

doi:10.1016/0022-0728(93)02926-9

Studies of solvated electrons in LiBr + HMPA solutions using the rotating ring-disk electrode technique. Part 2. The reaction of benzene with solvated electrons

P.J.M. Andel-Scheffer, van, A.H. Wonders, E. Barendrecht

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

By a rotating ring-disk electrode (RRDE) in LiBr+hexamethylphosphoramide (HMPA) solns. solvated electrons react very slowly with water, even at concns. >1M. The reaction of benzene with solvated electrons in LiBr+HMPA solns. takes place only in the presence of a proton donor such as water. A 2nd-order reaction rate const. was detd. for this reaction and is 0.26 * 103 M-1 s-1 at a disk current of -1.25 mA. [on SciFinder (R)]

Original language	English
Pages (from-to)	143-146
Journal	Journal of Electroanalytical Chemistry
Volume	366
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-0728(93)02926-9
Publication status	Published - 1994

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title = "Studies of solvated electrons in LiBr + HMPA solutions using the rotating ring-disk electrode technique. Part 2. The reaction of benzene with solvated electrons",

abstract = "By a rotating ring-disk electrode (RRDE) in LiBr+hexamethylphosphoramide (HMPA) solns. solvated electrons react very slowly with water, even at concns. >1M. The reaction of benzene with solvated electrons in LiBr+HMPA solns. takes place only in the presence of a proton donor such as water. A 2nd-order reaction rate const. was detd. for this reaction and is 0.26 * 103 M-1 s-1 at a disk current of -1.25 mA. [on SciFinder (R)]",

author = "{Andel-Scheffer, van}, P.J.M. and A.H. Wonders and E. Barendrecht",

year = "1994",

doi = "10.1016/0022-0728(93)02926-9",

language = "English",

volume = "366",

pages = "143--146",

journal = "Journal of Electroanalytical Chemistry",

issn = "0368-1874",

publisher = "Elsevier Sequoia",

number = "1-2",

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Studies of solvated electrons in LiBr + HMPA solutions using the rotating ring-disk electrode technique. Part 2. The reaction of benzene with solvated electrons. / Andel-Scheffer, van, P.J.M.; Wonders, A.H.; Barendrecht, E.

In: Journal of Electroanalytical Chemistry, Vol. 366, No. 1-2, 1994, p. 143-146.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - Studies of solvated electrons in LiBr + HMPA solutions using the rotating ring-disk electrode technique. Part 2. The reaction of benzene with solvated electrons

AU - Andel-Scheffer, van, P.J.M.

AU - Wonders, A.H.

AU - Barendrecht, E.

PY - 1994

Y1 - 1994

N2 - By a rotating ring-disk electrode (RRDE) in LiBr+hexamethylphosphoramide (HMPA) solns. solvated electrons react very slowly with water, even at concns. >1M. The reaction of benzene with solvated electrons in LiBr+HMPA solns. takes place only in the presence of a proton donor such as water. A 2nd-order reaction rate const. was detd. for this reaction and is 0.26 * 103 M-1 s-1 at a disk current of -1.25 mA. [on SciFinder (R)]

AB - By a rotating ring-disk electrode (RRDE) in LiBr+hexamethylphosphoramide (HMPA) solns. solvated electrons react very slowly with water, even at concns. >1M. The reaction of benzene with solvated electrons in LiBr+HMPA solns. takes place only in the presence of a proton donor such as water. A 2nd-order reaction rate const. was detd. for this reaction and is 0.26 * 103 M-1 s-1 at a disk current of -1.25 mA. [on SciFinder (R)]

U2 - 10.1016/0022-0728(93)02926-9

DO - 10.1016/0022-0728(93)02926-9

M3 - Article

SN - 0368-1874

VL - 366

SP - 143

EP - 146

JO - Journal of Electroanalytical Chemistry

JF - Journal of Electroanalytical Chemistry

IS - 1-2

ER -

Studies of solvated electrons in LiBr + HMPA solutions using the rotating ring-disk electrode technique. Part 2. The reaction of benzene with solvated electrons

Abstract

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