Structural, thermodynamic and electrochemical properties of over-stoichiometric La1-y(Ni1-zSnz) 5+2y hydride forming compounds

M. Latroche; A. Percheron-Guégan; P. H.L. Notten

doi:10.1016/j.jallcom.2004.01.026

Structural, thermodynamic and electrochemical properties of over-stoichiometric La_1-y(Ni_1-zSn_z) _5+2y hydride forming compounds

M. Latroche, A. Percheron-Guégan, P. H.L. Notten

Inorganic Materials & Catalysis

Research output: Contribution to journal › Article › Academic › peer-review

7 Citations (Scopus)

Abstract

The structural properties of four tin substituted La_1-y(Ni _1-zSn_z)_5+2y compounds have been investigated by X-ray powder diffraction (XRD) and microprobe analysis as a function of both tin amount (z) and over-stoichiometry (y). Their thermodynamic behaviour toward hydrogen gas absorption/desorption has been measured up to 1MPa. Their electrochemical capacities and cycle lives have been determined. From these analyses, the different behaviour observed for these materials have been correlated to their structural and thermodynamic properties.

Original language	English
Pages (from-to)	133-140
Number of pages	8
Journal	Journal of Alloys and Compounds
Volume	377
Issue number	1-2
DOIs	https://doi.org/10.1016/j.jallcom.2004.01.026
Publication status	Published - 8 Sept 2004

Keywords

AB
Electrochemical reactions
Electrochemistry
Gas-solid reactions
Hydrides
Hydrogen absorbing materials
Intermetallic compounds
Metal hydrides
Sn
X-ray diffraction

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10.1016/j.jallcom.2004.01.026

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abstract = "The structural properties of four tin substituted La1-y(Ni 1-zSnz)5+2y compounds have been investigated by X-ray powder diffraction (XRD) and microprobe analysis as a function of both tin amount (z) and over-stoichiometry (y). Their thermodynamic behaviour toward hydrogen gas absorption/desorption has been measured up to 1MPa. Their electrochemical capacities and cycle lives have been determined. From these analyses, the different behaviour observed for these materials have been correlated to their structural and thermodynamic properties.",

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T1 - Structural, thermodynamic and electrochemical properties of over-stoichiometric La1-y(Ni1-zSnz) 5+2y hydride forming compounds

AU - Latroche, M.

AU - Percheron-Guégan, A.

AU - Notten, P. H.L.

PY - 2004/9/8

Y1 - 2004/9/8

N2 - The structural properties of four tin substituted La1-y(Ni 1-zSnz)5+2y compounds have been investigated by X-ray powder diffraction (XRD) and microprobe analysis as a function of both tin amount (z) and over-stoichiometry (y). Their thermodynamic behaviour toward hydrogen gas absorption/desorption has been measured up to 1MPa. Their electrochemical capacities and cycle lives have been determined. From these analyses, the different behaviour observed for these materials have been correlated to their structural and thermodynamic properties.

AB - The structural properties of four tin substituted La1-y(Ni 1-zSnz)5+2y compounds have been investigated by X-ray powder diffraction (XRD) and microprobe analysis as a function of both tin amount (z) and over-stoichiometry (y). Their thermodynamic behaviour toward hydrogen gas absorption/desorption has been measured up to 1MPa. Their electrochemical capacities and cycle lives have been determined. From these analyses, the different behaviour observed for these materials have been correlated to their structural and thermodynamic properties.

KW - AB

KW - Electrochemical reactions

KW - Electrochemistry

KW - Gas-solid reactions

KW - Hydrides

KW - Hydrogen absorbing materials

KW - Intermetallic compounds

KW - Metal hydrides

KW - Sn

KW - X-ray diffraction

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DO - 10.1016/j.jallcom.2004.01.026

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SN - 0925-8388

VL - 377

SP - 133

EP - 140

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

IS - 1-2

ER -

Structural, thermodynamic and electrochemical properties of over-stoichiometric La_1-y(Ni_1-zSn_z) _5+2y hydride forming compounds

Abstract

Keywords

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