Abstract
The melt viscosity of poly(propylene) is found to reduce dramatically through the addition of a minute amount of silica nanoparticles. We attribute this unique effect to "selective adsorption of high molar mass polymer chains" on the surface of the nanofillers. This represents a paradigm shift regarding commonly-accepted relations between the molar mass and viscosity of molten polymers. This strong viscosity decrease provides major advantages for polymer processing and materials with improved properties are obtained.
Original language | English |
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Pages (from-to) | 1848-1854 |
Journal | Soft Matter |
Volume | 4 |
Issue number | 9 |
DOIs | |
Publication status | Published - 2008 |