Sterically demanding benzene-1,3,5-tricarboxamides : tuning the mechanisms of supramolecular polymerization and chiral amplification

M.A.J. Veld; D. Haveman; A.R.A. Palmans; E.W. Meijer

doi:10.1039/c0sm00516a

Sterically demanding benzene-1,3,5-tricarboxamides : tuning the mechanisms of supramolecular polymerization and chiral amplification

M.A.J. Veld, D. Haveman, A.R.A. Palmans, E.W. Meijer

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Abstract

Benzene-1,3,5-tricarboxamide (BTA) derivatives with one or three phenylalanine octyl ester (PheOct) moieties were synthesized and their supramolecular polymerization and chiral amplification behavior were investigated in mixing experiments between enantiomer pairs and in mixing with another, achiral BTA component. The incorporation of PheOct moieties is shown to have a major impact on the supramolecular self-assembly.

Original language	English
Pages (from-to)	524-531
Number of pages	8
Journal	Soft Matter
Volume	7
Issue number	2
DOIs	https://doi.org/10.1039/c0sm00516a
Publication status	Published - 2011

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AU - Palmans, A.R.A.

AU - Meijer, E.W.

PY - 2011

Y1 - 2011

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AB - Benzene-1,3,5-tricarboxamide (BTA) derivatives with one or three phenylalanine octyl ester (PheOct) moieties were synthesized and their supramolecular polymerization and chiral amplification behavior were investigated in mixing experiments between enantiomer pairs and in mixing with another, achiral BTA component. The incorporation of PheOct moieties is shown to have a major impact on the supramolecular self-assembly.

U2 - 10.1039/c0sm00516a

DO - 10.1039/c0sm00516a

M3 - Article

SN - 1744-683X

VL - 7

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EP - 531

JO - Soft Matter

JF - Soft Matter

IS - 2

ER -

Sterically demanding benzene-1,3,5-tricarboxamides : tuning the mechanisms of supramolecular polymerization and chiral amplification

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