Stereospecificity and stereochemistry of a thermal sigmatropic [1,5]-shift of an alkyl group

M.A.M. Boersma; J.W. Haan, de; H. Kloosterziel; L.J.M. Ven, van de

doi:10.1039/C29700001168

Stereospecificity and stereochemistry of a thermal sigmatropic [1,5]-shift of an alkyl group

M.A.M. Boersma
, J.W. Haan, de
, H. Kloosterziel
, L.J.M. Ven, van de

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

33 Citations (Scopus)

Abstract

Thermal isomerization of cis- and trans-6,9-dimethylspiro[4,4]nona-1,3-diene involves a suprafacial, sigmatropic [1,5]-shift of sp3 carbon, with retention of configuration.

Original language	English
Pages (from-to)	1168-1169
Journal	Journal of the Chemical Society [Section] D: Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/C29700001168
Publication status	Published - 1970

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title = "Stereospecificity and stereochemistry of a thermal sigmatropic [1,5]-shift of an alkyl group",

abstract = "Thermal isomerization of cis- and trans-6,9-dimethylspiro[4,4]nona-1,3-diene involves a suprafacial, sigmatropic [1,5]-shift of sp3 carbon, with retention of configuration.",

author = "M.A.M. Boersma and \{Haan, de\}, J.W. and H. Kloosterziel and \{Ven, van de\}, L.J.M.",

year = "1970",

doi = "10.1039/C29700001168",

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pages = "1168--1169",

journal = "Journal of the Chemical Society [Section] D: Chemical Communications",

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AU - Boersma, M.A.M.

AU - Haan, de, J.W.

AU - Kloosterziel, H.

AU - Ven, van de, L.J.M.

PY - 1970

Y1 - 1970

N2 - Thermal isomerization of cis- and trans-6,9-dimethylspiro[4,4]nona-1,3-diene involves a suprafacial, sigmatropic [1,5]-shift of sp3 carbon, with retention of configuration.

AB - Thermal isomerization of cis- and trans-6,9-dimethylspiro[4,4]nona-1,3-diene involves a suprafacial, sigmatropic [1,5]-shift of sp3 carbon, with retention of configuration.

U2 - 10.1039/C29700001168

DO - 10.1039/C29700001168

M3 - Article

SN - 0577-6171

SP - 1168

EP - 1169

JO - Journal of the Chemical Society [Section] D: Chemical Communications

JF - Journal of the Chemical Society [Section] D: Chemical Communications

IS - 18

ER -

Stereospecificity and stereochemistry of a thermal sigmatropic [1,5]-shift of an alkyl group

Abstract

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