Stereospecificity and stereochemistry of a thermal sigmatropic [1,5]-shift of an alkyl group

M.A.M. Boersma; J.W. Haan, de; H. Kloosterziel; L.J.M. Ven, van de

doi:10.1039/C29700001168

Stereospecificity and stereochemistry of a thermal sigmatropic [1,5]-shift of an alkyl group

M.A.M. Boersma, J.W. Haan, de, H. Kloosterziel, L.J.M. Ven, van de

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

Thermal isomerization of cis- and trans-6,9-dimethylspiro[4,4]nona-1,3-diene involves a suprafacial, sigmatropic [1,5]-shift of sp3 carbon, with retention of configuration.

Original language	English
Pages (from-to)	1168-1169
Journal	Journal of the Chemical Society [Section] D: Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/C29700001168
Publication status	Published - 1970

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title = "Stereospecificity and stereochemistry of a thermal sigmatropic [1,5]-shift of an alkyl group",

abstract = "Thermal isomerization of cis- and trans-6,9-dimethylspiro[4,4]nona-1,3-diene involves a suprafacial, sigmatropic [1,5]-shift of sp3 carbon, with retention of configuration.",

author = "M.A.M. Boersma and {Haan, de}, J.W. and H. Kloosterziel and {Ven, van de}, L.J.M.",

year = "1970",

doi = "10.1039/C29700001168",

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journal = "Journal of the Chemical Society [Section] D: Chemical Communications",

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AU - Ven, van de, L.J.M.

PY - 1970

Y1 - 1970

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AB - Thermal isomerization of cis- and trans-6,9-dimethylspiro[4,4]nona-1,3-diene involves a suprafacial, sigmatropic [1,5]-shift of sp3 carbon, with retention of configuration.

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DO - 10.1039/C29700001168

M3 - Article

SN - 0577-6171

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JO - Journal of the Chemical Society [Section] D: Chemical Communications

JF - Journal of the Chemical Society [Section] D: Chemical Communications

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Stereospecificity and stereochemistry of a thermal sigmatropic [1,5]-shift of an alkyl group

Abstract

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