Stereospecific quenching of the bicyclo[5.4.1]dodecapentaenyl cation. Evidence of orbital symmetry control

R.H.A.M. Brounts; P. Schipper; H.M. Buck

doi:10.1039/C39800000522

Stereospecific quenching of the bicyclo[5.4.1]dodecapentaenyl cation. Evidence of orbital symmetry control

R.H.A.M. Brounts, P. Schipper, H.M. Buck

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

4 Citations (Scopus)

Abstract

Quenching of the title cation (3) with lithium methoxide results in stereo- and regio-specific incorporation of the methoxy group to give (4); the high specificity of the quench reaction is controlled by orbital symmetry.

Original language	English
Pages (from-to)	522-524
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	11
DOIs	https://doi.org/10.1039/C39800000522
Publication status	Published - 1980

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title = "Stereospecific quenching of the bicyclo[5.4.1]dodecapentaenyl cation. Evidence of orbital symmetry control",

abstract = "Quenching of the title cation (3) with lithium methoxide results in stereo- and regio-specific incorporation of the methoxy group to give (4); the high specificity of the quench reaction is controlled by orbital symmetry.",

author = "R.H.A.M. Brounts and P. Schipper and H.M. Buck",

year = "1980",

doi = "10.1039/C39800000522",

language = "English",

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journal = "Journal of the Chemical Society, Chemical Communications",

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AU - Brounts, R.H.A.M.

AU - Schipper, P.

AU - Buck, H.M.

PY - 1980

Y1 - 1980

N2 - Quenching of the title cation (3) with lithium methoxide results in stereo- and regio-specific incorporation of the methoxy group to give (4); the high specificity of the quench reaction is controlled by orbital symmetry.

AB - Quenching of the title cation (3) with lithium methoxide results in stereo- and regio-specific incorporation of the methoxy group to give (4); the high specificity of the quench reaction is controlled by orbital symmetry.

U2 - 10.1039/C39800000522

DO - 10.1039/C39800000522

M3 - Article

SN - 0022-4936

SP - 522

EP - 524

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 11

ER -

Stereospecific quenching of the bicyclo[5.4.1]dodecapentaenyl cation. Evidence of orbital symmetry control

Abstract

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