Stereospecific quenching of the bicyclo[5.4.1]dodecapentaenyl cation. Evidence of orbital symmetry control

R.H.A.M. Brounts, P. Schipper, H.M. Buck

Research output: Contribution to journalArticleAcademicpeer-review

4 Citations (Scopus)

Abstract

Quenching of the title cation (3) with lithium methoxide results in stereo- and regio-specific incorporation of the methoxy group to give (4); the high specificity of the quench reaction is controlled by orbital symmetry.
Original languageEnglish
Pages (from-to)522-524
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number11
DOIs
Publication statusPublished - 1980

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