Steam cracking of hydrocarbons: 2 pyrolysis of methylcyclohexane

M. Bajus; V. Vesely; P.A. Leclercq; J.A. Rijks

doi:10.1021%2Fi360070a012

Steam cracking of hydrocarbons: 2 pyrolysis of methylcyclohexane

M. Bajus, V. Vesely, P.A. Leclercq, J.A. Rijks

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

20 Citations (Scopus)

77 Downloads (Pure)

Abstract

The thermal decomposition of methylcyclohexane in the presence of steam was studied in a laboratory tubular reactor with large inner surface at atmospheric pressure. Experimental data were obtained at a temperature range of 700-790 OC and at residence times of 0.04-0.20 s. The overall kinetic analysis gives a value of 201.3 kJ mol-' for the activation energy and 0.532 X 10" s-' for the frequency factor. The pyrolysis products (more than 90) were identified with capillary gas chromatography by comparison of their retention indices with those of standard hydrocarbons and by mass spectrometry.

Original language	English
Pages (from-to)	135-142
Number of pages	8
Journal	Industrial and Engineering Chemistry. Product Research and Development
Volume	18
Issue number	2
DOIs	https://doi.org/10.1021%2Fi360070a012
Publication status	Published - 1979

Access to Document

10.1021%2Fi360070a012

Cite this

@article{a6b89957d3314f19b85a601e38cb5ef6,

title = "Steam cracking of hydrocarbons: 2 pyrolysis of methylcyclohexane",

abstract = "The thermal decomposition of methylcyclohexane in the presence of steam was studied in a laboratory tubular reactor with large inner surface at atmospheric pressure. Experimental data were obtained at a temperature range of 700-790 OC and at residence times of 0.04-0.20 s. The overall kinetic analysis gives a value of 201.3 kJ mol-' for the activation energy and 0.532 X 10{"} s-' for the frequency factor. The pyrolysis products (more than 90) were identified with capillary gas chromatography by comparison of their retention indices with those of standard hydrocarbons and by mass spectrometry.",

author = "M. Bajus and V. Vesely and P.A. Leclercq and J.A. Rijks",

year = "1979",

doi = "10.1021%2Fi360070a012",

language = "English",

volume = "18",

pages = "135--142",

journal = "Industrial and Engineering Chemistry. Product Research and Development",

issn = "0019-7890",

number = "2",

}

TY - JOUR

T1 - Steam cracking of hydrocarbons

T2 - 2 pyrolysis of methylcyclohexane

AU - Bajus, M.

AU - Vesely, V.

AU - Leclercq, P.A.

AU - Rijks, J.A.

PY - 1979

Y1 - 1979

N2 - The thermal decomposition of methylcyclohexane in the presence of steam was studied in a laboratory tubular reactor with large inner surface at atmospheric pressure. Experimental data were obtained at a temperature range of 700-790 OC and at residence times of 0.04-0.20 s. The overall kinetic analysis gives a value of 201.3 kJ mol-' for the activation energy and 0.532 X 10" s-' for the frequency factor. The pyrolysis products (more than 90) were identified with capillary gas chromatography by comparison of their retention indices with those of standard hydrocarbons and by mass spectrometry.

AB - The thermal decomposition of methylcyclohexane in the presence of steam was studied in a laboratory tubular reactor with large inner surface at atmospheric pressure. Experimental data were obtained at a temperature range of 700-790 OC and at residence times of 0.04-0.20 s. The overall kinetic analysis gives a value of 201.3 kJ mol-' for the activation energy and 0.532 X 10" s-' for the frequency factor. The pyrolysis products (more than 90) were identified with capillary gas chromatography by comparison of their retention indices with those of standard hydrocarbons and by mass spectrometry.

U2 - 10.1021%2Fi360070a012

DO - 10.1021%2Fi360070a012

M3 - Article

SN - 0019-7890

VL - 18

SP - 135

EP - 142

JO - Industrial and Engineering Chemistry. Product Research and Development

JF - Industrial and Engineering Chemistry. Product Research and Development

IS - 2

ER -

Steam cracking of hydrocarbons: 2 pyrolysis of methylcyclohexane

Abstract

Access to Document

Fingerprint

Cite this