Stability aspects and olefine adsorption properties of Bi2Mo2O9 and of the silica-supported Bi9PMo12O52 catalyst

P.A. Batist; J.F.H. Bouwens; I. Matsuura

doi:10.1016/0021-9517(74)90087-6

Stability aspects and olefine adsorption properties of Bi2Mo2O9 and of the silica-supported Bi9PMo12O52 catalyst

P.A. Batist, J.F.H. Bouwens, I. Matsuura

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

The adsorption of 1-butene and butadiene on Bi2Mo2O9 and on silica-supported Bi9PMo12O52 catalyst was measured. Both catalysts (in which the Erman phase is the major component) show weak single-site adsorptions of 1-butene and butadiene and a slow but strong adsorption of butadiene. Thermal decomposition of the Erman phase into Bi2O3 · 3MoO3 and Bi2O3 · MoO3 runs parallel with a change of the weak single-site type of adsorption into a dual-site type of adsorption, well known as belonging to the koechlinite phase. The silica-supported catalyst is thermally more stable than the Bi2Mo2O9 compound. The supported catalyst is found to be partially unstable if exposed to reduction-reoxidation conditions at 470 °C. Suggestions are given as to the role of P in silica-supported Bi-Mo catalyst.

Original language	English
Pages (from-to)	362-368
Number of pages	7
Journal	Journal of Catalysis
Volume	32
Issue number	3
DOIs	https://doi.org/10.1016/0021-9517(74)90087-6
Publication status	Published - 1974

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title = "Stability aspects and olefine adsorption properties of Bi2Mo2O9 and of the silica-supported Bi9PMo12O52 catalyst",

abstract = "The adsorption of 1-butene and butadiene on Bi2Mo2O9 and on silica-supported Bi9PMo12O52 catalyst was measured. Both catalysts (in which the Erman phase is the major component) show weak single-site adsorptions of 1-butene and butadiene and a slow but strong adsorption of butadiene. Thermal decomposition of the Erman phase into Bi2O3 · 3MoO3 and Bi2O3 · MoO3 runs parallel with a change of the weak single-site type of adsorption into a dual-site type of adsorption, well known as belonging to the koechlinite phase. The silica-supported catalyst is thermally more stable than the Bi2Mo2O9 compound. The supported catalyst is found to be partially unstable if exposed to reduction-reoxidation conditions at 470 °C. Suggestions are given as to the role of P in silica-supported Bi-Mo catalyst.",

author = "P.A. Batist and J.F.H. Bouwens and I. Matsuura",

year = "1974",

doi = "10.1016/0021-9517(74)90087-6",

language = "English",

volume = "32",

pages = "362--368",

journal = "Journal of Catalysis",

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TY - JOUR

T1 - Stability aspects and olefine adsorption properties of Bi2Mo2O9 and of the silica-supported Bi9PMo12O52 catalyst

AU - Batist, P.A.

AU - Bouwens, J.F.H.

AU - Matsuura, I.

PY - 1974

Y1 - 1974

N2 - The adsorption of 1-butene and butadiene on Bi2Mo2O9 and on silica-supported Bi9PMo12O52 catalyst was measured. Both catalysts (in which the Erman phase is the major component) show weak single-site adsorptions of 1-butene and butadiene and a slow but strong adsorption of butadiene. Thermal decomposition of the Erman phase into Bi2O3 · 3MoO3 and Bi2O3 · MoO3 runs parallel with a change of the weak single-site type of adsorption into a dual-site type of adsorption, well known as belonging to the koechlinite phase. The silica-supported catalyst is thermally more stable than the Bi2Mo2O9 compound. The supported catalyst is found to be partially unstable if exposed to reduction-reoxidation conditions at 470 °C. Suggestions are given as to the role of P in silica-supported Bi-Mo catalyst.

AB - The adsorption of 1-butene and butadiene on Bi2Mo2O9 and on silica-supported Bi9PMo12O52 catalyst was measured. Both catalysts (in which the Erman phase is the major component) show weak single-site adsorptions of 1-butene and butadiene and a slow but strong adsorption of butadiene. Thermal decomposition of the Erman phase into Bi2O3 · 3MoO3 and Bi2O3 · MoO3 runs parallel with a change of the weak single-site type of adsorption into a dual-site type of adsorption, well known as belonging to the koechlinite phase. The silica-supported catalyst is thermally more stable than the Bi2Mo2O9 compound. The supported catalyst is found to be partially unstable if exposed to reduction-reoxidation conditions at 470 °C. Suggestions are given as to the role of P in silica-supported Bi-Mo catalyst.

U2 - 10.1016/0021-9517(74)90087-6

DO - 10.1016/0021-9517(74)90087-6

M3 - Article

SN - 0021-9517

VL - 32

SP - 362

EP - 368

JO - Journal of Catalysis

JF - Journal of Catalysis

IS - 3

ER -

Stability aspects and olefine adsorption properties of Bi2Mo2O9 and of the silica-supported Bi9PMo12O52 catalyst

Abstract

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