Solventless liquid oligoesters analyzed by MALDI-ToF-MS

R.X.E. Willemse, W. Ming, A.M. Herk, van

Research output: Contribution to journalArticleAcademicpeer-review

4 Citations (Scopus)

Abstract

MALDI-ToF-MS mass spectra of copolymers contain a lot of information on both chain-length distribution (CLD) and chemical composition distribution (CCD). In this paper, two random solventless liquid oligoesters were synthesized by an esterification of 1,4-butanediol with adipic acid and isophthalic acid or glutaric acid, respectively. The thus obtained oligoesters contain two different repeat units and may therefore be regarded as a copolymer. A copolymer fingerprint analysis has been used to study the microstructure of the copolymers for which it was observed that the copolymers can be described very well using Bernoullian chain statistics.
Original languageEnglish
Pages (from-to)6876-6881
JournalMacromolecules
Volume38
Issue number16
DOIs
Publication statusPublished - 2005

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