Solvent effects on the π-dimerization of cation radicals of conjugated oligomers

Joke J. Apperloo; René A.J. Janssen

doi:10.1016/S0379-6779(98)00760-7

Solvent effects on the π-dimerization of cation radicals of conjugated oligomers

Joke J. Apperloo
, René A.J. Janssen

Research output: Contribution to journal › Article › Academic › peer-review

13 Citations (Scopus)

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Abstract

π-Dimerization of cation radicals of conjugated oligomers has been investigated in various solvents to assess the effect of the polarity of the medium on the dimerization enthalpy. It is found that π-dimerization is favored in less polar solvents, unless solubilizing substituents are present.

Original language	English
Pages (from-to)	373-374
Number of pages	2
Journal	Synthetic Metals
Volume	101
Issue number	1-3
DOIs	https://doi.org/10.1016/S0379-6779(98)00760-7
Publication status	Published - 1 Dec 1999

Keywords

π-Dimers
Cation radicals
Pyrrole oligomers
Thiophene oligomers
UV/Vis/nearIR spectroscopy

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10.1016/S0379-6779(98)00760-7

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title = "Solvent effects on the π-dimerization of cation radicals of conjugated oligomers",

abstract = "π-Dimerization of cation radicals of conjugated oligomers has been investigated in various solvents to assess the effect of the polarity of the medium on the dimerization enthalpy. It is found that π-dimerization is favored in less polar solvents, unless solubilizing substituents are present.",

keywords = "π-Dimers, Cation radicals, Pyrrole oligomers, Thiophene oligomers, UV/Vis/nearIR spectroscopy",

author = "Apperloo, \{Joke J.\} and Janssen, \{Ren{\'e} A.J.\}",

year = "1999",

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doi = "10.1016/S0379-6779(98)00760-7",

language = "English",

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pages = "373--374",

journal = "Synthetic Metals",

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T1 - Solvent effects on the π-dimerization of cation radicals of conjugated oligomers

AU - Apperloo, Joke J.

AU - Janssen, René A.J.

PY - 1999/12/1

Y1 - 1999/12/1

N2 - π-Dimerization of cation radicals of conjugated oligomers has been investigated in various solvents to assess the effect of the polarity of the medium on the dimerization enthalpy. It is found that π-dimerization is favored in less polar solvents, unless solubilizing substituents are present.

AB - π-Dimerization of cation radicals of conjugated oligomers has been investigated in various solvents to assess the effect of the polarity of the medium on the dimerization enthalpy. It is found that π-dimerization is favored in less polar solvents, unless solubilizing substituents are present.

KW - π-Dimers

KW - Cation radicals

KW - Pyrrole oligomers

KW - Thiophene oligomers

KW - UV/Vis/nearIR spectroscopy

UR - https://www.scopus.com/pages/publications/0032597236

U2 - 10.1016/S0379-6779(98)00760-7

DO - 10.1016/S0379-6779(98)00760-7

M3 - Article

SN - 0379-6779

VL - 101

SP - 373

EP - 374

JO - Synthetic Metals

JF - Synthetic Metals

IS - 1-3

ER -

Solvent effects on the π-dimerization of cation radicals of conjugated oligomers

Abstract

Keywords

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