Single crystal ESR study of x-irradiated 2-chloro-2,2'-spirobis(1,3,2-benzodioxaphosphole): phosphorus in an octahedral geometry with the unpaired electron and chlorine in axial positions

J.H.H. Hamerlinck, P. Schipper, H.M. Buck

Research output: Contribution to journalArticleAcademicpeer-review

5 Citations (Scopus)

Abstract

X-irradiation of a single crystal of 2-chloro-2,2'-spirobis(1,3,2-benzodioxaphosphole) yields the oriented PVI radical anion formed by electron capture. Directions of maximum values of the magnetic hyperfine tensors of 31P, 35Cl, and 37Cl are coincident and oriented along the P—Cl linkage, indicating an octahedral structure with the unpaired electron and chlorine in axial positions.
Original languageEnglish
Pages (from-to)358-360
Number of pages3
JournalChemical Physics Letters
Volume80
Issue number2
DOIs
Publication statusPublished - 1981

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