Single crystal e.s.r. study of the octahydro-2a,4a,6a,8a-tetra-aza-8b-phospha(V)pentaleno[1,6-cd]pentalen-8b-yl radical. Evidence of ligand exchange via a Berry pseudorotation mechanism

J.H.H. Hamerlinck; P.H.H. Hermkens; P. Schipper; H.M. Buck

doi:10.1039/C39810000358

Single crystal e.s.r. study of the octahydro-2a,4a,6a,8a-tetra-aza-8b-phospha(V)pentaleno[1,6-cd]pentalen-8b-yl radical. Evidence of ligand exchange via a Berry pseudorotation mechanism

J.H.H. Hamerlinck
, P.H.H. Hermkens
, P. Schipper
, H.M. Buck

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

9 Citations (Scopus)

1 Downloads (Pure)

Abstract

The nitrogen ligands of the title phosphoranyl radical interconvert pairwise via an M-1 Berry pseudo-rotation mechanism in the solid state.

Original language	English
Pages (from-to)	358-360
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/C39810000358
Publication status	Published - 1981

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Hamerlinck, J. H. H., Hermkens, P. H. H., Schipper, P., & Buck, H. M. (1981). Single crystal e.s.r. study of the octahydro-2a,4a,6a,8a-tetra-aza-8b-phospha(V)pentaleno[1,6-cd]pentalen-8b-yl radical. Evidence of ligand exchange via a Berry pseudorotation mechanism. Journal of the Chemical Society, Chemical Communications, (8), 358-360. https://doi.org/10.1039/C39810000358

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title = "Single crystal e.s.r. study of the octahydro-2a,4a,6a,8a-tetra-aza-8b-phospha(V)pentaleno[1,6-cd]pentalen-8b-yl radical. Evidence of ligand exchange via a Berry pseudorotation mechanism",

abstract = "The nitrogen ligands of the title phosphoranyl radical interconvert pairwise via an M-1 Berry pseudo-rotation mechanism in the solid state.",

author = "J.H.H. Hamerlinck and P.H.H. Hermkens and P. Schipper and H.M. Buck",

year = "1981",

doi = "10.1039/C39810000358",

language = "English",

pages = "358--360",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "8",

}

Single crystal e.s.r. study of the octahydro-2a,4a,6a,8a-tetra-aza-8b-phospha(V)pentaleno[1,6-cd]pentalen-8b-yl radical. Evidence of ligand exchange via a Berry pseudorotation mechanism. / Hamerlinck, J.H.H.; Hermkens, P.H.H.; Schipper, P. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 8, 1981, p. 358-360.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - Single crystal e.s.r. study of the octahydro-2a,4a,6a,8a-tetra-aza-8b-phospha(V)pentaleno[1,6-cd]pentalen-8b-yl radical. Evidence of ligand exchange via a Berry pseudorotation mechanism

AU - Hamerlinck, J.H.H.

AU - Hermkens, P.H.H.

AU - Schipper, P.

AU - Buck, H.M.

PY - 1981

Y1 - 1981

N2 - The nitrogen ligands of the title phosphoranyl radical interconvert pairwise via an M-1 Berry pseudo-rotation mechanism in the solid state.

AB - The nitrogen ligands of the title phosphoranyl radical interconvert pairwise via an M-1 Berry pseudo-rotation mechanism in the solid state.

U2 - 10.1039/C39810000358

DO - 10.1039/C39810000358

M3 - Article

SN - 0022-4936

SP - 358

EP - 360

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 8

ER -

Single crystal e.s.r. study of the octahydro-2a,4a,6a,8a-tetra-aza-8b-phospha(V)pentaleno[1,6-cd]pentalen-8b-yl radical. Evidence of ligand exchange via a Berry pseudorotation mechanism

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