Single crystal e.s.r. study of the octahydro-2a,4a,6a,8a-tetra-aza-8b-phospha(V)pentaleno[1,6-cd]pentalen-8b-yl radical. Evidence of ligand exchange via a Berry pseudorotation mechanism

J.H.H. Hamerlinck, P.H.H. Hermkens, P. Schipper, H.M. Buck

Research output: Contribution to journalArticleAcademicpeer-review

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Abstract

The nitrogen ligands of the title phosphoranyl radical interconvert pairwise via an M-1 Berry pseudo-rotation mechanism in the solid state.
Original languageEnglish
Pages (from-to)358-360
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number8
DOIs
Publication statusPublished - 1981

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