Side-chain degradation of ultrapure π-conjugated oligomers: implications for organic electronics

R.J. Abbel; M. Wolffs; R.A.A. Bovee; J.L.J. Dongen, van; X.W. Lou; O. Henze; W.J. Feast; E.W. Meijer; A.P.H.J. Schenning

doi:10.1002/adma.200802416

Side-chain degradation of ultrapure π-conjugated oligomers: implications for organic electronics

R.J. Abbel, M. Wolffs, R.A.A. Bovee, J.L.J. Dongen, van, X.W. Lou, O. Henze, W.J. Feast, E.W. Meijer, A.P.H.J. Schenning

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Abstract

The degrdn. of two defect-free pi-conjugated oligomers and the participation of their solubilizing side chains in the process are studied in unprecedented detail. The detected intermediate products reveal a mechanism of successive shortening of alkyl and oligo(ethylene glycol) substituents. Eventually, these processes cause chem. modifications in the conjugated backbone, which strongly influence the electronic properties of the materials.

Original language	English
Pages (from-to)	597-602
Journal	Advanced Materials
Volume	21
Issue number	5
DOIs	https://doi.org/10.1002/adma.200802416
Publication status	Published - 2009

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title = "Side-chain degradation of ultrapure π-conjugated oligomers: implications for organic electronics",

abstract = "The degrdn. of two defect-free pi-conjugated oligomers and the participation of their solubilizing side chains in the process are studied in unprecedented detail. The detected intermediate products reveal a mechanism of successive shortening of alkyl and oligo(ethylene glycol) substituents. Eventually, these processes cause chem. modifications in the conjugated backbone, which strongly influence the electronic properties of the materials.",

author = "R.J. Abbel and M. Wolffs and R.A.A. Bovee and {Dongen, van}, J.L.J. and X.W. Lou and O. Henze and W.J. Feast and E.W. Meijer and A.P.H.J. Schenning",

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AU - Abbel, R.J.

AU - Wolffs, M.

AU - Bovee, R.A.A.

AU - Dongen, van, J.L.J.

AU - Lou, X.W.

AU - Henze, O.

AU - Feast, W.J.

AU - Meijer, E.W.

AU - Schenning, A.P.H.J.

PY - 2009

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AB - The degrdn. of two defect-free pi-conjugated oligomers and the participation of their solubilizing side chains in the process are studied in unprecedented detail. The detected intermediate products reveal a mechanism of successive shortening of alkyl and oligo(ethylene glycol) substituents. Eventually, these processes cause chem. modifications in the conjugated backbone, which strongly influence the electronic properties of the materials.

U2 - 10.1002/adma.200802416

DO - 10.1002/adma.200802416

M3 - Article

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VL - 21

SP - 597

EP - 602

JO - Advanced Materials

JF - Advanced Materials

IS - 5

ER -

Side-chain degradation of ultrapure π-conjugated oligomers: implications for organic electronics

Abstract

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