Selective photochemical isomerizations of E,E-germacra-1(10),4,7(11)-trien-8-one

P.J.M. Reijnders, H.M. Buck

Research output: Contribution to journalArticleAcademicpeer-review

5 Citations (Scopus)

Abstract

Direct irradiation of title compound 1 causes isomerization of the 1(10)-double bond to give the 1(10)Z,4E-isomer 2, due to selective energy transfer in the ß,-enone fragment formed by the carbonyl group and the 1(10)-double bond. Acetophenone-sensitized irradiation in n-hexane leads to the completely isomerized 1(10)Z,4Z-germacrone 3. 1(10)E,4Z-Germacrone could not be prepared photochemically.
Original languageEnglish
Pages (from-to)263-264
Number of pages2
JournalRecueil des Travaux Chimiques des Pays-Bas
Volume97
Issue number10
DOIs
Publication statusPublished - 1978

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