Selective oxidation of methyl alpha-D-glucoside on carbon supported platinum II. Assessment of the Arrhenius and Langmuir parameters

Y.J.B.M. Schuurman; B.F.M. Kuster; K. Wiele, van der; G.B.M.M. Marin

doi:10.1016/0926-860X(92)80076-O

Selective oxidation of methyl alpha-D-glucoside on carbon supported platinum II. Assessment of the Arrhenius and Langmuir parameters

Y.J.B.M. Schuurman, B.F.M. Kuster, K. Wiele, van der, G.B.M.M. Marin

Chemical Reactor Engineering

Research output: Contribution to journal › Article › Academic › peer-review

34 Citations (Scopus)

183 Downloads (Pure)

Abstract

In order to est. the Arrhenius Langmuir parameters of the selective oxidn. of Me a-D-glucoside I on a Pt catalyst, the temp. was varied from 293 to 333 K. The initial reaction kinetics can be described adequately over this temp. range by Langmuir-Hinshelwood rate equation which is based on two parallel paths: one involving adsorbed I and dominating at low pH, the other involving the adsorbed I-anion and dominating at high pH. Langmuir adsorption coeffs. account for the reversible dissociative chemisorption of oxygen and for the reversible associative adsorption of I and I-anion

Original language	English
Pages (from-to)	31-46
Journal	Applied Catalysis. A, General
Volume	89
Issue number	1
DOIs	https://doi.org/10.1016/0926-860X(92)80076-O
Publication status	Published - 1992

Access to Document

10.1016/0926-860X(92)80076-O

621163Final published version, 983 KB

Cite this

@article{b56602eab0f340b596b9e2620cbfbac5,

title = "Selective oxidation of methyl alpha-D-glucoside on carbon supported platinum II. Assessment of the Arrhenius and Langmuir parameters",

abstract = "In order to est. the Arrhenius Langmuir parameters of the selective oxidn. of Me a-D-glucoside I on a Pt catalyst, the temp. was varied from 293 to 333 K. The initial reaction kinetics can be described adequately over this temp. range by Langmuir-Hinshelwood rate equation which is based on two parallel paths: one involving adsorbed I and dominating at low pH, the other involving the adsorbed I-anion and dominating at high pH. Langmuir adsorption coeffs. account for the reversible dissociative chemisorption of oxygen and for the reversible associative adsorption of I and I-anion",

author = "Y.J.B.M. Schuurman and B.F.M. Kuster and {Wiele, van der}, K. and G.B.M.M. Marin",

year = "1992",

doi = "10.1016/0926-860X(92)80076-O",

language = "English",

volume = "89",

pages = "31--46",

journal = "Applied Catalysis. A, General",

issn = "0926-860X",

publisher = "Elsevier B.V.",

number = "1",

}

TY - JOUR

T1 - Selective oxidation of methyl alpha-D-glucoside on carbon supported platinum II. Assessment of the Arrhenius and Langmuir parameters

AU - Schuurman, Y.J.B.M.

AU - Kuster, B.F.M.

AU - Wiele, van der, K.

AU - Marin, G.B.M.M.

PY - 1992

Y1 - 1992

N2 - In order to est. the Arrhenius Langmuir parameters of the selective oxidn. of Me a-D-glucoside I on a Pt catalyst, the temp. was varied from 293 to 333 K. The initial reaction kinetics can be described adequately over this temp. range by Langmuir-Hinshelwood rate equation which is based on two parallel paths: one involving adsorbed I and dominating at low pH, the other involving the adsorbed I-anion and dominating at high pH. Langmuir adsorption coeffs. account for the reversible dissociative chemisorption of oxygen and for the reversible associative adsorption of I and I-anion

AB - In order to est. the Arrhenius Langmuir parameters of the selective oxidn. of Me a-D-glucoside I on a Pt catalyst, the temp. was varied from 293 to 333 K. The initial reaction kinetics can be described adequately over this temp. range by Langmuir-Hinshelwood rate equation which is based on two parallel paths: one involving adsorbed I and dominating at low pH, the other involving the adsorbed I-anion and dominating at high pH. Langmuir adsorption coeffs. account for the reversible dissociative chemisorption of oxygen and for the reversible associative adsorption of I and I-anion

U2 - 10.1016/0926-860X(92)80076-O

DO - 10.1016/0926-860X(92)80076-O

M3 - Article

SN - 0926-860X

VL - 89

SP - 31

EP - 46

JO - Applied Catalysis. A, General

JF - Applied Catalysis. A, General

IS - 1

ER -

Selective oxidation of methyl alpha-D-glucoside on carbon supported platinum II. Assessment of the Arrhenius and Langmuir parameters

Abstract

Access to Document

Fingerprint

Cite this