Selective oxidation of ammonia to nitrogen over silica supported molybdena catalysts. A structure-selectivity relationship

  • M. Boer, de
  • , A.J. Dillen, van
  • , D.C. Koningsberger
  • , F.J.J.G. Janssen
  • , T. Koerts
  • , J.W. Geus

    Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademicpeer-review

    Abstract

    The selective catalytic oxidn. of NH3 to N2 over unsupported and SiO2-supported MoO3 catalysts was investigated. The defect structure of the catalysts greatly affects the selectivity towards N2O. The performance of the SiO2-supported catalysts is controlled by the thermal pretreatment and the structure, which is detd. by the prepn. procedure. Water dramatically decreases the selectivity to N2 of MoO3-SiO2 catalysts with low loadings. The selectivity to N2 highly depends on the ability of the catalyst to decomp. released N2O, which proceeds on oxygen vacancies. [on SciFinder (R)]
    Original languageEnglish
    Title of host publicationNew Dev. Sel. Oxid. Heterog. Catal.
    Pages133-145
    DOIs
    Publication statusPublished - 1992

    Publication series

    NameStudies in Surface Science and Catalysis
    Volume72
    ISSN (Print)0167-2991

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