Selective Methanethiol-to-Olefins Conversion over HSSZ-13 Zeolite’

Miao Yu; Nicolo Tormene; Aleksei  Bolshakov; Brahim Mezari; Anna Liutkova; Nikolay Kosinov; Emiel J.M. Hensen

doi:10.1039/D1CC00397F

Selective Methanethiol-to-Olefins Conversion over HSSZ-13 Zeolite’

Miao Yu, Nicolo Tormene, Aleksei Bolshakov, Brahim Mezari, Anna Liutkova, Nikolay Kosinov (Corresponding author), Emiel J.M. Hensen (Corresponding author)

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Abstract

A methanethiol-to-olefins (MtTO) equivalent of methanol-to-olefins (MTO) chemistry is demonstrated. CH3SH can be converted to ethylene and propylene in a similar manner as CH3OH over SSZ-13 zeolite involving a hydrocarbon pool mechansim. Methylated aromatic intermediates were identified by 13C NMR analysis. Comparison of MtTO and MTO chemistry provides clues about the mechanism of C–C bond formation and catalyst deactivation.

Original language	English
Pages (from-to)	3323-3326
Number of pages	4
Journal	Chemical Communications, ChemComm
Volume	57
Issue number	27
DOIs	https://doi.org/10.1039/D1CC00397F
Publication status	Published - 7 Apr 2021

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10.1039/D1CC00397F

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title = "Selective Methanethiol-to-Olefins Conversion over HSSZ-13 Zeolite{\textquoteright}",

abstract = "A methanethiol-to-olefins (MtTO) equivalent of methanol-to-olefins (MTO) chemistry is demonstrated. CH3SH can be converted to ethylene and propylene in a similar manner as CH3OH over SSZ-13 zeolite involving a hydrocarbon pool mechansim. Methylated aromatic intermediates were identified by 13C NMR analysis. Comparison of MtTO and MTO chemistry provides clues about the mechanism of C–C bond formation and catalyst deactivation.",

author = "Miao Yu and Nicolo Tormene and Aleksei Bolshakov and Brahim Mezari and Anna Liutkova and Nikolay Kosinov and Hensen, {Emiel J.M.}",

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doi = "10.1039/D1CC00397F",

language = "English",

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TY - JOUR

T1 - Selective Methanethiol-to-Olefins Conversion over HSSZ-13 Zeolite’

AU - Yu, Miao

AU - Tormene, Nicolo

AU - Bolshakov, Aleksei

AU - Mezari, Brahim

AU - Liutkova, Anna

AU - Kosinov, Nikolay

AU - Hensen, Emiel J.M.

PY - 2021/4/7

Y1 - 2021/4/7

N2 - A methanethiol-to-olefins (MtTO) equivalent of methanol-to-olefins (MTO) chemistry is demonstrated. CH3SH can be converted to ethylene and propylene in a similar manner as CH3OH over SSZ-13 zeolite involving a hydrocarbon pool mechansim. Methylated aromatic intermediates were identified by 13C NMR analysis. Comparison of MtTO and MTO chemistry provides clues about the mechanism of C–C bond formation and catalyst deactivation.

AB - A methanethiol-to-olefins (MtTO) equivalent of methanol-to-olefins (MTO) chemistry is demonstrated. CH3SH can be converted to ethylene and propylene in a similar manner as CH3OH over SSZ-13 zeolite involving a hydrocarbon pool mechansim. Methylated aromatic intermediates were identified by 13C NMR analysis. Comparison of MtTO and MTO chemistry provides clues about the mechanism of C–C bond formation and catalyst deactivation.

UR - http://www.scopus.com/inward/record.url?scp=85103493767&partnerID=8YFLogxK

U2 - 10.1039/D1CC00397F

DO - 10.1039/D1CC00397F

M3 - Article

SN - 1359-7345

VL - 57

SP - 3323

EP - 3326

JO - Chemical Communications, ChemComm

JF - Chemical Communications, ChemComm

IS - 27

ER -

Selective Methanethiol-to-Olefins Conversion over HSSZ-13 Zeolite’

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