Selective low temperature NH3 oxidation to N2 on copper-based catalysts

L. Gang, J. Grondelle, van, B.G. Anderson, R.A. Santen, van

Research output: Contribution to journalArticleAcademicpeer-review

124 Citations (Scopus)
3 Downloads (Pure)


TPD, TPR, UV-visible spectroscopy, and high-resolution electron microscopy (HREM) have been used to characterize the state and reactivity of alumina-supported copper-based catalysts for the oxidation of ammonia to nitrogen. The results of HREM and UV spectra show that a CuAl2O4-like phase is more active than a CuO phase for the ammonia oxidation reaction. Both surface oxygen and copper lattice oxygen can react with NH3 to produce N-2 but surface oxygen is much more active than lattice oxygen at low temperature. For copper zeolite catalysts [Cu-O-Cu](2+)- like species or small copper oxygen aggregates are the likely forms of the catalytically active centers at low temperature. The activity of CuY was increased by treating the sample with NaOH. This treatment presumably increases the amount of low temperature active centers.
Original languageEnglish
Pages (from-to)100-109
Number of pages10
JournalJournal of Catalysis
Issue number1
Publication statusPublished - 1999


Dive into the research topics of 'Selective low temperature NH3 oxidation to N2 on copper-based catalysts'. Together they form a unique fingerprint.

Cite this