Abstract
The observation is reported of satn. with chain length of the 2nd hyperpolarizability of a series of long defined conjugated oligothiophenes. This satn. occurs at the same length as that of the band gap and of the polarizability, and is attributed to a satn. of the effective conjugation length. Solvatochromic and thermochromic measurements indicate that conformational effects play a role. [on SciFinder (R)]
| Original language | English |
|---|---|
| Pages (from-to) | 2141-2144 |
| Number of pages | 4 |
| Journal | Physical Review Letters |
| Volume | 65 |
| Issue number | 17 |
| DOIs | |
| Publication status | Published - 1990 |
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