RuCl2[S-BINAP]-catalyzed synthesis of aldehydes and ketones by dehydrogenation of alcohols

R.H. Meijer, G.B.W.L. Ligthart, J. Meuldijk, J.A.J.M. Vekemans, L.A. Hulshof

Research output: Contribution to journalArticleAcademicpeer-review

7 Citations (Scopus)

Abstract

RuCl2[S-BINAP] catalyzed dehydrogenation of alcs. into aldehydes or ketones has been investigated. Among many H-acceptors screened, diphenylacetylene (tolane) was the most suitable judged from its smooth redn. Electron rich and deficient analogs of tolane have been synthesized. Based on competition expts. between these H-acceptors a tentative catalytic cycle for the RuCl2[S-BINAP] catalyzed dehydrogenations is proposed. [on SciFinder (R)]
Original languageEnglish
Pages (from-to)29-40
JournalJournal of Molecular Catalysis A: Chemical
Volume218
Issue number1
DOIs
Publication statusPublished - 2004

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