RuCl2[S-BINAP]-catalyzed synthesis of aldehydes and ketones by dehydrogenation of alcohols

R.H. Meijer; G.B.W.L. Ligthart; J. Meuldijk; J.A.J.M. Vekemans; L.A. Hulshof

doi:10.1016/j.molcata.2004.04.003

RuCl2[S-BINAP]-catalyzed synthesis of aldehydes and ketones by dehydrogenation of alcohols

R.H. Meijer, G.B.W.L. Ligthart, J. Meuldijk, J.A.J.M. Vekemans, L.A. Hulshof

Research output: Contribution to journal › Article › Academic › peer-review

7 Citations (Scopus)

Abstract

RuCl2[S-BINAP] catalyzed dehydrogenation of alcs. into aldehydes or ketones has been investigated. Among many H-acceptors screened, diphenylacetylene (tolane) was the most suitable judged from its smooth redn. Electron rich and deficient analogs of tolane have been synthesized. Based on competition expts. between these H-acceptors a tentative catalytic cycle for the RuCl2[S-BINAP] catalyzed dehydrogenations is proposed. [on SciFinder (R)]

Original language	English
Pages (from-to)	29-40
Journal	Journal of Molecular Catalysis A: Chemical
Volume	218
Issue number	1
DOIs	https://doi.org/10.1016/j.molcata.2004.04.003
Publication status	Published - 2004

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10.1016/j.molcata.2004.04.003

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title = "RuCl2[S-BINAP]-catalyzed synthesis of aldehydes and ketones by dehydrogenation of alcohols",

abstract = "RuCl2[S-BINAP] catalyzed dehydrogenation of alcs. into aldehydes or ketones has been investigated. Among many H-acceptors screened, diphenylacetylene (tolane) was the most suitable judged from its smooth redn. Electron rich and deficient analogs of tolane have been synthesized. Based on competition expts. between these H-acceptors a tentative catalytic cycle for the RuCl2[S-BINAP] catalyzed dehydrogenations is proposed. [on SciFinder (R)]",

author = "R.H. Meijer and G.B.W.L. Ligthart and J. Meuldijk and J.A.J.M. Vekemans and L.A. Hulshof",

year = "2004",

doi = "10.1016/j.molcata.2004.04.003",

language = "English",

volume = "218",

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journal = "Journal of Molecular Catalysis A: Chemical",

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TY - JOUR

T1 - RuCl2[S-BINAP]-catalyzed synthesis of aldehydes and ketones by dehydrogenation of alcohols

AU - Meijer, R.H.

AU - Ligthart, G.B.W.L.

AU - Meuldijk, J.

AU - Vekemans, J.A.J.M.

AU - Hulshof, L.A.

PY - 2004

Y1 - 2004

N2 - RuCl2[S-BINAP] catalyzed dehydrogenation of alcs. into aldehydes or ketones has been investigated. Among many H-acceptors screened, diphenylacetylene (tolane) was the most suitable judged from its smooth redn. Electron rich and deficient analogs of tolane have been synthesized. Based on competition expts. between these H-acceptors a tentative catalytic cycle for the RuCl2[S-BINAP] catalyzed dehydrogenations is proposed. [on SciFinder (R)]

AB - RuCl2[S-BINAP] catalyzed dehydrogenation of alcs. into aldehydes or ketones has been investigated. Among many H-acceptors screened, diphenylacetylene (tolane) was the most suitable judged from its smooth redn. Electron rich and deficient analogs of tolane have been synthesized. Based on competition expts. between these H-acceptors a tentative catalytic cycle for the RuCl2[S-BINAP] catalyzed dehydrogenations is proposed. [on SciFinder (R)]

U2 - 10.1016/j.molcata.2004.04.003

DO - 10.1016/j.molcata.2004.04.003

M3 - Article

SN - 1381-1169

VL - 218

SP - 29

EP - 40

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

IS - 1

ER -

RuCl2[S-BINAP]-catalyzed synthesis of aldehydes and ketones by dehydrogenation of alcohols

Abstract

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