Reversible metallo-supramolecular block copolymer micelles containing a soft core

J.M.W. Gohy; B.G.G. Lohmeijer; U.S. Schubert

doi:10.1002/1521-3927(20020601)23:9<555::AID-MARC555>3.0.CO;2-K

Reversible metallo-supramolecular block copolymer micelles containing a soft core

J.M.W. Gohy, B.G.G. Lohmeijer, U.S. Schubert

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

115 Citations (Scopus)

Abstract

An amphiphilic metallo-supramol. poly(ethylene-co-butylene)-block-poly(ethylene oxide) diblock copolymer contg. a bis(2,2':6',2''-terpyridine)ruthenium(II) complex as a supramol. connection between the two constituting blocks was used to prep. stable aq. micelles. The micelles were characterized by dynamic light scattering and at. force microscopy. Individual micelles were obsd. together with aggregates of micelles. Only the addn. of a large excess of competitive ligand caused the cleavage of the very stable ruthenium complex

Original language	English
Pages (from-to)	555-560
Number of pages	5
Journal	Macromolecular Rapid Communications
Volume	23
Issue number	9
DOIs	https://doi.org/10.1002/1521-3927(20020601)23:9<555::AID-MARC555>3.0.CO;2-K
Publication status	Published - 2002

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10.1002/1521-3927(20020601)23:9<555::AID-MARC555>3.0.CO;2-K

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title = "Reversible metallo-supramolecular block copolymer micelles containing a soft core",

abstract = "An amphiphilic metallo-supramol. poly(ethylene-co-butylene)-block-poly(ethylene oxide) diblock copolymer contg. a bis(2,2':6',2''-terpyridine)ruthenium(II) complex as a supramol. connection between the two constituting blocks was used to prep. stable aq. micelles. The micelles were characterized by dynamic light scattering and at. force microscopy. Individual micelles were obsd. together with aggregates of micelles. Only the addn. of a large excess of competitive ligand caused the cleavage of the very stable ruthenium complex",

author = "J.M.W. Gohy and B.G.G. Lohmeijer and U.S. Schubert",

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AU - Gohy, J.M.W.

AU - Lohmeijer, B.G.G.

AU - Schubert, U.S.

PY - 2002

Y1 - 2002

N2 - An amphiphilic metallo-supramol. poly(ethylene-co-butylene)-block-poly(ethylene oxide) diblock copolymer contg. a bis(2,2':6',2''-terpyridine)ruthenium(II) complex as a supramol. connection between the two constituting blocks was used to prep. stable aq. micelles. The micelles were characterized by dynamic light scattering and at. force microscopy. Individual micelles were obsd. together with aggregates of micelles. Only the addn. of a large excess of competitive ligand caused the cleavage of the very stable ruthenium complex

AB - An amphiphilic metallo-supramol. poly(ethylene-co-butylene)-block-poly(ethylene oxide) diblock copolymer contg. a bis(2,2':6',2''-terpyridine)ruthenium(II) complex as a supramol. connection between the two constituting blocks was used to prep. stable aq. micelles. The micelles were characterized by dynamic light scattering and at. force microscopy. Individual micelles were obsd. together with aggregates of micelles. Only the addn. of a large excess of competitive ligand caused the cleavage of the very stable ruthenium complex

U2 - 10.1002/1521-3927(20020601)23:9<555::AID-MARC555>3.0.CO;2-K

DO - 10.1002/1521-3927(20020601)23:9<555::AID-MARC555>3.0.CO;2-K

M3 - Article

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VL - 23

SP - 555

EP - 560

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 9

ER -

Reversible metallo-supramolecular block copolymer micelles containing a soft core

Abstract

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