Reversible mechanochemistry of a PdII coordination polymer

J.M.J. Paulusse; R.P. Sijbesma

doi:10.1002/anie.200460040

Reversible mechanochemistry of a PdII coordination polymer

J.M.J. Paulusse, R.P. Sijbesma

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Abstract

Breaking up and making up: The ultrasonic cleavage of high-molecular-weight linear coordination polymers of phosphane telechelic polytetrahydrofuran and palladium dichloride in dilute solution is a reversible process (see picture). Sonication for 1 h led to a decrease in the weight-averaged molecular weight of the polymer from 1.7×105 to 1.0×105 g mol-1. Upon leaving the sample to stand for 24 h, the original molecular weight was completely restored.

Original language	English
Pages (from-to)	4460-4462
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	34
DOIs	https://doi.org/10.1002/anie.200460040
Publication status	Published - 2004

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title = "Reversible mechanochemistry of a PdII coordination polymer",

abstract = "Breaking up and making up: The ultrasonic cleavage of high-molecular-weight linear coordination polymers of phosphane telechelic polytetrahydrofuran and palladium dichloride in dilute solution is a reversible process (see picture). Sonication for 1 h led to a decrease in the weight-averaged molecular weight of the polymer from 1.7×105 to 1.0×105 g mol-1. Upon leaving the sample to stand for 24 h, the original molecular weight was completely restored.",

author = "J.M.J. Paulusse and R.P. Sijbesma",

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AB - Breaking up and making up: The ultrasonic cleavage of high-molecular-weight linear coordination polymers of phosphane telechelic polytetrahydrofuran and palladium dichloride in dilute solution is a reversible process (see picture). Sonication for 1 h led to a decrease in the weight-averaged molecular weight of the polymer from 1.7×105 to 1.0×105 g mol-1. Upon leaving the sample to stand for 24 h, the original molecular weight was completely restored.

U2 - 10.1002/anie.200460040

DO - 10.1002/anie.200460040

M3 - Article

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SP - 4460

EP - 4462

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 34

ER -

Reversible mechanochemistry of a PdII coordination polymer

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