Relation between the structure of organic compounds and their retention time in gas chromatography

J.J. Walraven; A.W. Ladon; A.I.M. Keulemans

Relation between the structure of organic compounds and their retention time in gas chromatography

J.J. Walraven, A.W. Ladon, A.I.M. Keulemans

Chemical Engineering and Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

Abstract

Retention indexes of alkanes and alkenes on 2 stationary phases (octadecene and dimethylsulfolane, at 25 Deg) were plotted on diagrams in which the index on an apolar phase is one and the index on a polar phase is the other axis. Branched isomers were spread along parallel lines in a repeated pattern; the \"roofing tile effect.\" Data were also plotted for Me carboxylates, the stationary phases being squalane and polypropylene sebacate, for C13-19 cyclohexyl and Ph alkanes Apiezon and polyphenyl ether; there was a const. shift due to change of cyclohexyl to Ph. A close relationship was found between structure and retention time of isomeric pentanols, hexanols, cycloalkanes, and alkenes. [on SciFinder (R)]

Original language	English
Title of host publication	Int. Symp. Chromatogr. Electrophoresis 5th
Pages	138-145
Publication status	Published - 1969

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@inproceedings{6e8646c3b9a24659a2a890910afc0458,

title = "Relation between the structure of organic compounds and their retention time in gas chromatography",

abstract = "Retention indexes of alkanes and alkenes on 2 stationary phases (octadecene and dimethylsulfolane, at 25 Deg) were plotted on diagrams in which the index on an apolar phase is one and the index on a polar phase is the other axis. Branched isomers were spread along parallel lines in a repeated pattern; the \{"}roofing tile effect.\{"} Data were also plotted for Me carboxylates, the stationary phases being squalane and polypropylene sebacate, for C13-19 cyclohexyl and Ph alkanes Apiezon and polyphenyl ether; there was a const. shift due to change of cyclohexyl to Ph. A close relationship was found between structure and retention time of isomeric pentanols, hexanols, cycloalkanes, and alkenes. [on SciFinder (R)]",

author = "J.J. Walraven and A.W. Ladon and A.I.M. Keulemans",

year = "1969",

language = "English",

pages = "138--145",

booktitle = "Int. Symp. Chromatogr. Electrophoresis 5th",

}

TY - GEN

T1 - Relation between the structure of organic compounds and their retention time in gas chromatography

AU - Walraven, J.J.

AU - Ladon, A.W.

AU - Keulemans, A.I.M.

PY - 1969

Y1 - 1969

N2 - Retention indexes of alkanes and alkenes on 2 stationary phases (octadecene and dimethylsulfolane, at 25 Deg) were plotted on diagrams in which the index on an apolar phase is one and the index on a polar phase is the other axis. Branched isomers were spread along parallel lines in a repeated pattern; the \"roofing tile effect.\" Data were also plotted for Me carboxylates, the stationary phases being squalane and polypropylene sebacate, for C13-19 cyclohexyl and Ph alkanes Apiezon and polyphenyl ether; there was a const. shift due to change of cyclohexyl to Ph. A close relationship was found between structure and retention time of isomeric pentanols, hexanols, cycloalkanes, and alkenes. [on SciFinder (R)]

AB - Retention indexes of alkanes and alkenes on 2 stationary phases (octadecene and dimethylsulfolane, at 25 Deg) were plotted on diagrams in which the index on an apolar phase is one and the index on a polar phase is the other axis. Branched isomers were spread along parallel lines in a repeated pattern; the \"roofing tile effect.\" Data were also plotted for Me carboxylates, the stationary phases being squalane and polypropylene sebacate, for C13-19 cyclohexyl and Ph alkanes Apiezon and polyphenyl ether; there was a const. shift due to change of cyclohexyl to Ph. A close relationship was found between structure and retention time of isomeric pentanols, hexanols, cycloalkanes, and alkenes. [on SciFinder (R)]

M3 - Conference contribution

SP - 138

EP - 145

BT - Int. Symp. Chromatogr. Electrophoresis 5th

ER -