Reductive ring cleavage of 1,3-disubstituted imidazolium iodides by sodium borohydride

E.F. Godefroi

doi:10.1021/jo01266a089

Reductive ring cleavage of 1,3-disubstituted imidazolium iodides by sodium borohydride

E.F. Godefroi

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

22 Citations (Scopus)

Abstract

The effect of NaBH4 on some simple, dissimilarly substituted imidazolium iodides with a benzyl substituent on 1 of the N atoms was investigated. In all cases, reductive ring cleavage occurred giving 2 isomers which were sepd. by their HCl salts. NaBH4 cleaves the imidazolium ring predominantly between the C-2 and the N atom bearing the benzyl group.

Original language	English
Pages (from-to)	860-862
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	33
Issue number	2
DOIs	https://doi.org/10.1021/jo01266a089
Publication status	Published - 1968

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title = "Reductive ring cleavage of 1,3-disubstituted imidazolium iodides by sodium borohydride",

abstract = "The effect of NaBH4 on some simple, dissimilarly substituted imidazolium iodides with a benzyl substituent on 1 of the N atoms was investigated. In all cases, reductive ring cleavage occurred giving 2 isomers which were sepd. by their HCl salts. NaBH4 cleaves the imidazolium ring predominantly between the C-2 and the N atom bearing the benzyl group.",

author = "E.F. Godefroi",

year = "1968",

doi = "10.1021/jo01266a089",

language = "English",

volume = "33",

pages = "860--862",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "2",

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T1 - Reductive ring cleavage of 1,3-disubstituted imidazolium iodides by sodium borohydride

AU - Godefroi, E.F.

PY - 1968

Y1 - 1968

N2 - The effect of NaBH4 on some simple, dissimilarly substituted imidazolium iodides with a benzyl substituent on 1 of the N atoms was investigated. In all cases, reductive ring cleavage occurred giving 2 isomers which were sepd. by their HCl salts. NaBH4 cleaves the imidazolium ring predominantly between the C-2 and the N atom bearing the benzyl group.

AB - The effect of NaBH4 on some simple, dissimilarly substituted imidazolium iodides with a benzyl substituent on 1 of the N atoms was investigated. In all cases, reductive ring cleavage occurred giving 2 isomers which were sepd. by their HCl salts. NaBH4 cleaves the imidazolium ring predominantly between the C-2 and the N atom bearing the benzyl group.

U2 - 10.1021/jo01266a089

DO - 10.1021/jo01266a089

M3 - Article

SN - 0022-3263

VL - 33

SP - 860

EP - 862

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 2

ER -

Reductive ring cleavage of 1,3-disubstituted imidazolium iodides by sodium borohydride

Abstract

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