Reductive elimination and skeletal rearrangement of b-hydroxy selenide derivatives of bicyclo[4.2.1]nonatriene in a super acid medium

H.M.J. Gillissen, P. Schipper, H.M. Buck

Research output: Contribution to journalArticleAcademicpeer-review

4 Citations (Scopus)

Abstract

In sulfur dioxide the ß-hydroxy selenides 1 and 2 produce rearranged selenides 6 and 7 upon addition of fluorosulfonic acid. Reductive elimination and subsequent attack of the selenenyl electrophile on the etheno bridge cause migration of the butadiene moiety.
Original languageEnglish
Pages (from-to)346-348
JournalRecueil des Travaux Chimiques des Pays-Bas
Volume99
Issue number11
DOIs
Publication statusPublished - 1980

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