Real-time reaction control for solar production of chemicals under fluctuating irradiance

F. Zhao, D. Cambié, V. Hessel, M.G. Debije, T. Noël

Research output: Contribution to journalArticleAcademicpeer-review

14 Citations (Scopus)
19 Downloads (Pure)

Abstract

Arguably, one of the major practical barriers hampering a wider use of solar energy to promote photochemical reactions are the variations in sunlight intensity at different times of the day as well as the fluctuations caused by passing clouds. Herein, we present an automatically responsive reaction control system enabling solar photochemistry under vastly changeable irradiance conditions. While the luminescent solar concentrator photomicroreactor (LSC-PM) design converts solar light into a narrow and steady spectral distribution, this reaction control system, inspired by the Quality by Design approach, maintains the reaction conversion constant at a set target value by dynamically changing the residence time in the reactor. The superior efficiency of an LSC-PM equipped with this reaction control system is shown both with artificially generated light fluctuations and in outdoor experiments using sunlight.

Original languageEnglish
Pages (from-to)2459-2464
Number of pages6
JournalGreen Chemistry
Volume20
Issue number11
DOIs
Publication statusPublished - 24 Apr 2018

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irradiance
Solar concentrators
control system
Photochemical reactions
Control systems
photochemistry
Solar energy
residence time
chemical
experiment
Experiments
distribution
reactor
solar energy
photochemical reaction

Cite this

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Real-time reaction control for solar production of chemicals under fluctuating irradiance. / Zhao, F.; Cambié, D.; Hessel, V.; Debije, M.G.; Noël, T.

In: Green Chemistry, Vol. 20, No. 11, 24.04.2018, p. 2459-2464.

Research output: Contribution to journalArticleAcademicpeer-review

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T1 - Real-time reaction control for solar production of chemicals under fluctuating irradiance

AU - Zhao, F.

AU - Cambié, D.

AU - Hessel, V.

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