Reaction routes for methane conversion on transition metals at low temperature

T. Koerts; R.A. Santen, van

doi:10.1016/S0167-2991(08)64434-1

Reaction routes for methane conversion on transition metals at low temperature

T. Koerts
, R.A. Santen, van

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

19 Citations (Scopus)

262 Downloads (Pure)

Abstract

Two new metal catalysed routes for methane conversion are discussed: methane oligomerization and methane addition to olefins. These reactions are realized in a reaction cycle consisting of several steps. In both reaction sequences methane is first dissociatively adsorbed on a reduced transition metal catalyst between 500 and 800 K resulting in surface carbon and hydrogen. A particular highly reactive surface carbonaceous intermediate is found to produce C2+ hydrocarbons upon hydrogenation between 300 and 400 K. The maximum yield for higher hydrocarbons is 13% obtained on a Ru/SiO2 catalyst. When olefins are co-adsorbed together with surface carbon generated from methane, more C2+ hydrocarbons are produced. Experiments with 13C labelled CH4 and unlabelled olefins demonstrate that surface carbon from methane is incorporated into the co-adsorbed olefins.

Original language	English
Title of host publication	New frontiers in catalysis : proceedings of the 10th International Congress on Catalysis, Budapest
Editors	L. Guczi, F. Solymosi, P. Tétényi
Place of Publication	Amsterdam
Publisher	Elsevier
Pages	1065-1078
Number of pages	14
ISBN (Print)	0-444-89621-X
DOIs	https://doi.org/10.1016/S0167-2991(08)64434-1
Publication status	Published - 1993
Event	10th International Congress on Catalysis (ICC 1992) - Budapest, Hungary Duration: 19 Jul 1992 → 24 Jul 1992 Conference number: 10

Publication series

Name	Studies in Surface Science and Catalysis
Volume	75
ISSN (Print)	0167-2991

Conference

Conference	10th International Congress on Catalysis (ICC 1992)
Abbreviated title	ICC 1992
Country/Territory	Hungary
City	Budapest
Period	19/07/92 → 24/07/92

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10.1016/S0167-2991(08)64434-1

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Koerts, T., & Santen, van, R. A. (1993). Reaction routes for methane conversion on transition metals at low temperature. In L. Guczi, F. Solymosi, & P. Tétényi (Eds.), New frontiers in catalysis : proceedings of the 10th International Congress on Catalysis, Budapest (pp. 1065-1078). (Studies in Surface Science and Catalysis; Vol. 75). Elsevier. https://doi.org/10.1016/S0167-2991(08)64434-1

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title = "Reaction routes for methane conversion on transition metals at low temperature",

abstract = "Two new metal catalysed routes for methane conversion are discussed: methane oligomerization and methane addition to olefins. These reactions are realized in a reaction cycle consisting of several steps. In both reaction sequences methane is first dissociatively adsorbed on a reduced transition metal catalyst between 500 and 800 K resulting in surface carbon and hydrogen. A particular highly reactive surface carbonaceous intermediate is found to produce C2+ hydrocarbons upon hydrogenation between 300 and 400 K. The maximum yield for higher hydrocarbons is 13\% obtained on a Ru/SiO2 catalyst. When olefins are co-adsorbed together with surface carbon generated from methane, more C2+ hydrocarbons are produced. Experiments with 13C labelled CH4 and unlabelled olefins demonstrate that surface carbon from methane is incorporated into the co-adsorbed olefins.",

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note = "10th International Congress on Catalysis (ICC 1992), ICC 1992 ; Conference date: 19-07-1992 Through 24-07-1992",

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Koerts, T & Santen, van, RA 1993, Reaction routes for methane conversion on transition metals at low temperature. in L Guczi, F Solymosi & P Tétényi (eds), New frontiers in catalysis : proceedings of the 10th International Congress on Catalysis, Budapest. Studies in Surface Science and Catalysis, vol. 75, Elsevier, Amsterdam, pp. 1065-1078, 10th International Congress on Catalysis (ICC 1992), Budapest, Hungary, 19/07/92. https://doi.org/10.1016/S0167-2991(08)64434-1

Reaction routes for methane conversion on transition metals at low temperature. / Koerts, T.; Santen, van, R.A.
New frontiers in catalysis : proceedings of the 10th International Congress on Catalysis, Budapest. ed. / L. Guczi; F. Solymosi; P. Tétényi. Amsterdam: Elsevier, 1993. p. 1065-1078 (Studies in Surface Science and Catalysis; Vol. 75).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

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T1 - Reaction routes for methane conversion on transition metals at low temperature

AU - Koerts, T.

AU - Santen, van, R.A.

N1 - Conference code: 10

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N2 - Two new metal catalysed routes for methane conversion are discussed: methane oligomerization and methane addition to olefins. These reactions are realized in a reaction cycle consisting of several steps. In both reaction sequences methane is first dissociatively adsorbed on a reduced transition metal catalyst between 500 and 800 K resulting in surface carbon and hydrogen. A particular highly reactive surface carbonaceous intermediate is found to produce C2+ hydrocarbons upon hydrogenation between 300 and 400 K. The maximum yield for higher hydrocarbons is 13% obtained on a Ru/SiO2 catalyst. When olefins are co-adsorbed together with surface carbon generated from methane, more C2+ hydrocarbons are produced. Experiments with 13C labelled CH4 and unlabelled olefins demonstrate that surface carbon from methane is incorporated into the co-adsorbed olefins.

AB - Two new metal catalysed routes for methane conversion are discussed: methane oligomerization and methane addition to olefins. These reactions are realized in a reaction cycle consisting of several steps. In both reaction sequences methane is first dissociatively adsorbed on a reduced transition metal catalyst between 500 and 800 K resulting in surface carbon and hydrogen. A particular highly reactive surface carbonaceous intermediate is found to produce C2+ hydrocarbons upon hydrogenation between 300 and 400 K. The maximum yield for higher hydrocarbons is 13% obtained on a Ru/SiO2 catalyst. When olefins are co-adsorbed together with surface carbon generated from methane, more C2+ hydrocarbons are produced. Experiments with 13C labelled CH4 and unlabelled olefins demonstrate that surface carbon from methane is incorporated into the co-adsorbed olefins.

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DO - 10.1016/S0167-2991(08)64434-1

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T3 - Studies in Surface Science and Catalysis

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Koerts T, Santen, van RA. Reaction routes for methane conversion on transition metals at low temperature. In Guczi L, Solymosi F, Tétényi P, editors, New frontiers in catalysis : proceedings of the 10th International Congress on Catalysis, Budapest. Amsterdam: Elsevier. 1993. p. 1065-1078. (Studies in Surface Science and Catalysis). doi: 10.1016/S0167-2991(08)64434-1

Reaction routes for methane conversion on transition metals at low temperature

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