Quasi-chemical approximation for nonrandomness in the hole theory of polymeric fluids. 1. Equation of state behavior of pure components

E. Nies; Hankun Xie

doi:10.1021/ma00059a030

Quasi-chemical approximation for nonrandomness in the hole theory of polymeric fluids. 1. Equation of state behavior of pure components

E. Nies, Hankun Xie

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Abstract

The effect of nonrandomness is introduced in the Holey Huggins hole theory (a modified version of the Simha-Somcynsky theory) based on the quasichem. approxn. of Guggenheim. The resulting nonrandomness is dependent on the energetic interactions and is detd. by the so-called free vol. contributions typical of cell and hole theories. The theory offers an accurate description of exptl. equation of state data of polymers and small mols. A comparison with the random mixing analog of the present theory shows that the introduction of the quasichem. approxn. improves the accuracy of the description of exptl. data. [on SciFinder (R)]

Original language	English
Pages (from-to)	1683-1688
Journal	Macromolecules
Volume	26
Issue number	7
DOIs	https://doi.org/10.1021/ma00059a030
Publication status	Published - 1993

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title = "Quasi-chemical approximation for nonrandomness in the hole theory of polymeric fluids. 1. Equation of state behavior of pure components",

abstract = "The effect of nonrandomness is introduced in the Holey Huggins hole theory (a modified version of the Simha-Somcynsky theory) based on the quasichem. approxn. of Guggenheim. The resulting nonrandomness is dependent on the energetic interactions and is detd. by the so-called free vol. contributions typical of cell and hole theories. The theory offers an accurate description of exptl. equation of state data of polymers and small mols. A comparison with the random mixing analog of the present theory shows that the introduction of the quasichem. approxn. improves the accuracy of the description of exptl. data. [on SciFinder (R)]",

author = "E. Nies and Hankun Xie",

year = "1993",

doi = "10.1021/ma00059a030",

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volume = "26",

pages = "1683--1688",

journal = "Macromolecules",

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publisher = "American Chemical Society",

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T1 - Quasi-chemical approximation for nonrandomness in the hole theory of polymeric fluids. 1. Equation of state behavior of pure components

AU - Nies, E.

AU - Xie, Hankun

PY - 1993

Y1 - 1993

N2 - The effect of nonrandomness is introduced in the Holey Huggins hole theory (a modified version of the Simha-Somcynsky theory) based on the quasichem. approxn. of Guggenheim. The resulting nonrandomness is dependent on the energetic interactions and is detd. by the so-called free vol. contributions typical of cell and hole theories. The theory offers an accurate description of exptl. equation of state data of polymers and small mols. A comparison with the random mixing analog of the present theory shows that the introduction of the quasichem. approxn. improves the accuracy of the description of exptl. data. [on SciFinder (R)]

AB - The effect of nonrandomness is introduced in the Holey Huggins hole theory (a modified version of the Simha-Somcynsky theory) based on the quasichem. approxn. of Guggenheim. The resulting nonrandomness is dependent on the energetic interactions and is detd. by the so-called free vol. contributions typical of cell and hole theories. The theory offers an accurate description of exptl. equation of state data of polymers and small mols. A comparison with the random mixing analog of the present theory shows that the introduction of the quasichem. approxn. improves the accuracy of the description of exptl. data. [on SciFinder (R)]

U2 - 10.1021/ma00059a030

DO - 10.1021/ma00059a030

M3 - Article

SN - 0024-9297

VL - 26

SP - 1683

EP - 1688

JO - Macromolecules

JF - Macromolecules

IS - 7

ER -

Quasi-chemical approximation for nonrandomness in the hole theory of polymeric fluids. 1. Equation of state behavior of pure components

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