Abstract
Ab initio quantum-chemical cluster calculations demonstrate that the activated complexes of hydride transfer reaction in catalytic transformations of paraffins on zeolites very much resembles adsorbed nonclassical carbonium ions. The calculated activation energies for reactions involving propane and isobutane are in reasonable agreement with experimental data.
Original language | English |
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Title of host publication | Progress in zeolite and microporous materials : proceedings of the 11th International Zeolite Conference, Seoul, Korea |
Editors | H. Chon, S.-K. Ihm, Y.S. Uh |
Place of Publication | Amsterdam |
Publisher | Elsevier |
Pages | 2283-2290 |
Number of pages | 8 |
ISBN (Print) | 0-444-82344-1 |
DOIs | |
Publication status | Published - 1997 |
Event | 11th International Zeolite conference - Seoul, Korea, Democratic People's Republic of Duration: 12 Aug 1996 → 17 Aug 1996 Conference number: 11 |
Publication series
Name | Studies in Surface Science and Catalysis |
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Publisher | Elsevier |
Volume | 105C |
ISSN (Print) | 0167-2991 |
Conference
Conference | 11th International Zeolite conference |
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Abbreviated title | IZC |
Country/Territory | Korea, Democratic People's Republic of |
City | Seoul |
Period | 12/08/96 → 17/08/96 |
Other | 11th International Zeolite conference, Seoul, Korea, 12-17-August 1996 |