In this study some aspects of quantitation in capillary gas chromatography are discussed for on-column and cold temperature proqrammed sample inlet systems. Discrimination due to differences in volatility, polarity and concentration of the solutes will be evaluated and compared for both systems. A mixture of n-alkanes with hydrocarbon numbers between 8 and 32 and a test mixture normally used for column quality control are used for this purpose.
It will be shown that at optimal operating conditions highly accurate results can be achieved for samples with a wide range of volatility, polarity and concentration.
|Title of host publication||Ninth International Symposium on Capillary Chromatography, Monterey, California, USA|
|Place of Publication||Heidelberg|
|Publication status||Published - 1988|
|Event||9th International Symposium on Capillary Chromatography - Conference Center, Monterey, United States|
Duration: 16 May 1988 → 19 May 1988
|Conference||9th International Symposium on Capillary Chromatography|
|Period||16/05/88 → 19/05/88|