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Quadratic Nonlinear Optical Properties of Correlated Chromophores: Cyclic 6,6'-Dinitro-1,1'-Binaphthyl-2,2'-Ethers

  • E.H.J. Hendrickx
  • , C. Boutton
  • , K. Clays
  • , A.P. Persoons
  • , J.J.G.S. Es, van
  • , H.A.M. Biemans
  • , E.W. Meijer

Research output: Contribution to journalArticleAcademicpeer-review

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Abstract

The first hyperpolarizability, , of a series of cyclic 6,6¿-dinitro-1,1¿-binaphthyl-2,2¿-ethers has been analyzed with hyper-Rayleigh scattering and electric-field-induced second-harmonic-generation and compared with the absorption data and semi-empirical calculations. The results show the critical dependence of on the conformation of the alkoxy donor and the dihedral angle of the binaphthyl unit.
Original languageEnglish
Pages (from-to)241-244
Number of pages4
JournalChemical Physics Letters
Volume270
Issue number1-2
DOIs
Publication statusPublished - 1997

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