Quadratic Nonlinear Optical Properties of Correlated Chromophores: Cyclic 6,6'-Dinitro-1,1'-Binaphthyl-2,2'-Ethers

E.H.J. Hendrickx; C. Boutton; K. Clays; A.P. Persoons; J.J.G.S. Es, van; H.A.M. Biemans; E.W. Meijer

doi:10.1016/S0009-2614(97)00325-4

Quadratic Nonlinear Optical Properties of Correlated Chromophores: Cyclic 6,6'-Dinitro-1,1'-Binaphthyl-2,2'-Ethers

E.H.J. Hendrickx, C. Boutton, K. Clays, A.P. Persoons, J.J.G.S. Es, van, H.A.M. Biemans, E.W. Meijer

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Abstract

The first hyperpolarizability, , of a series of cyclic 6,6¿-dinitro-1,1¿-binaphthyl-2,2¿-ethers has been analyzed with hyper-Rayleigh scattering and electric-field-induced second-harmonic-generation and compared with the absorption data and semi-empirical calculations. The results show the critical dependence of on the conformation of the alkoxy donor and the dihedral angle of the binaphthyl unit.

Original language	English
Pages (from-to)	241-244
Number of pages	4
Journal	Chemical Physics Letters
Volume	270
Issue number	1-2
DOIs	https://doi.org/10.1016/S0009-2614(97)00325-4
Publication status	Published - 1997

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title = "Quadratic Nonlinear Optical Properties of Correlated Chromophores: Cyclic 6,6'-Dinitro-1,1'-Binaphthyl-2,2'-Ethers",

abstract = "The first hyperpolarizability, , of a series of cyclic 6,6¿-dinitro-1,1¿-binaphthyl-2,2¿-ethers has been analyzed with hyper-Rayleigh scattering and electric-field-induced second-harmonic-generation and compared with the absorption data and semi-empirical calculations. The results show the critical dependence of on the conformation of the alkoxy donor and the dihedral angle of the binaphthyl unit.",

author = "E.H.J. Hendrickx and C. Boutton and K. Clays and A.P. Persoons and {Es, van}, J.J.G.S. and H.A.M. Biemans and E.W. Meijer",

year = "1997",

doi = "10.1016/S0009-2614(97)00325-4",

language = "English",

volume = "270",

pages = "241--244",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier B.V.",

number = "1-2",

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TY - JOUR

T1 - Quadratic Nonlinear Optical Properties of Correlated Chromophores: Cyclic 6,6'-Dinitro-1,1'-Binaphthyl-2,2'-Ethers

AU - Hendrickx, E.H.J.

AU - Boutton, C.

AU - Clays, K.

AU - Persoons, A.P.

AU - Es, van, J.J.G.S.

AU - Biemans, H.A.M.

AU - Meijer, E.W.

PY - 1997

Y1 - 1997

N2 - The first hyperpolarizability, , of a series of cyclic 6,6¿-dinitro-1,1¿-binaphthyl-2,2¿-ethers has been analyzed with hyper-Rayleigh scattering and electric-field-induced second-harmonic-generation and compared with the absorption data and semi-empirical calculations. The results show the critical dependence of on the conformation of the alkoxy donor and the dihedral angle of the binaphthyl unit.

AB - The first hyperpolarizability, , of a series of cyclic 6,6¿-dinitro-1,1¿-binaphthyl-2,2¿-ethers has been analyzed with hyper-Rayleigh scattering and electric-field-induced second-harmonic-generation and compared with the absorption data and semi-empirical calculations. The results show the critical dependence of on the conformation of the alkoxy donor and the dihedral angle of the binaphthyl unit.

U2 - 10.1016/S0009-2614(97)00325-4

DO - 10.1016/S0009-2614(97)00325-4

M3 - Article

SN - 0009-2614

VL - 270

SP - 241

EP - 244

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1-2

ER -

Quadratic Nonlinear Optical Properties of Correlated Chromophores: Cyclic 6,6'-Dinitro-1,1'-Binaphthyl-2,2'-Ethers

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