Pulsed-laser studies on the free-radical polymerization kinetics of styrene in microemulsion

L.G. Manders; A.M. Herk, van; A.L. German; J. Sarnecki; R. Schomäcker; J. Schweer

doi:10.1002/marc.1993.030141103

Pulsed-laser studies on the free-radical polymerization kinetics of styrene in microemulsion

L.G. Manders, A.M. Herk, van, A.L. German, J. Sarnecki, R. Schomäcker, J. Schweer

Chemical Engineering and Chemistry

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Abstract

A mean value of 339 L mol-1 s-1 was obtained for the propagation const. derived from pulsed-laser polymn. (PLP) of styrene in aq. AOT microemulsions. For accurate detns., simulations accounting for the esp. high radical concn. after the laser pulse in microemulsions were recommended. PLP with microemulsions apparently permitted specific kinetic aspects such as transfer to monomer and influence of droplet size on bimol. termination to be studied in detail

Original language	English
Pages (from-to)	693-701
Journal	Makromolekulare Chemie, Rapid Communications
Volume	14
Issue number	11
DOIs	https://doi.org/10.1002/marc.1993.030141103
Publication status	Published - 1993

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title = "Pulsed-laser studies on the free-radical polymerization kinetics of styrene in microemulsion",

abstract = "A mean value of 339 L mol-1 s-1 was obtained for the propagation const. derived from pulsed-laser polymn. (PLP) of styrene in aq. AOT microemulsions. For accurate detns., simulations accounting for the esp. high radical concn. after the laser pulse in microemulsions were recommended. PLP with microemulsions apparently permitted specific kinetic aspects such as transfer to monomer and influence of droplet size on bimol. termination to be studied in detail",

author = "L.G. Manders and {Herk, van}, A.M. and A.L. German and J. Sarnecki and R. Schom{\"a}cker and J. Schweer",

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AU - Manders, L.G.

AU - Herk, van, A.M.

AU - German, A.L.

AU - Sarnecki, J.

AU - Schomäcker, R.

AU - Schweer, J.

PY - 1993

Y1 - 1993

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AB - A mean value of 339 L mol-1 s-1 was obtained for the propagation const. derived from pulsed-laser polymn. (PLP) of styrene in aq. AOT microemulsions. For accurate detns., simulations accounting for the esp. high radical concn. after the laser pulse in microemulsions were recommended. PLP with microemulsions apparently permitted specific kinetic aspects such as transfer to monomer and influence of droplet size on bimol. termination to be studied in detail

U2 - 10.1002/marc.1993.030141103

DO - 10.1002/marc.1993.030141103

M3 - Article

SN - 0173-2803

VL - 14

SP - 693

EP - 701

JO - Makromolekulare Chemie, Rapid Communications

JF - Makromolekulare Chemie, Rapid Communications

IS - 11

ER -

Pulsed-laser studies on the free-radical polymerization kinetics of styrene in microemulsion

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