Promotion by vanadium compound of the elementary reaction steps in the synthesis gas reaction catalyzed by rhodium

T. Koerts, W.J.J. Welters, R.A. Santen, van, L.E.Y. Nonneman, V. Ponec

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademicpeer-review

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Abstract

In order to understand the promoting effect of V compd. on Rh catalysts in synthesis gas conversion, changes in reaction rates of elementary steps and the surface concn. of intermediates have been monitored. V promotion enhances the rate of CO dissocn. which is the most important effect. Reactive surface carbon is stabilized by V which results in a slightly decreased reactivity in methane formation. Transient expts. using isotopes and GCMS detection show that CO insertion is not promoted by V. The hydrogenation of ethanal to ethanol is enhanced by V while the desorption rate of ethanal is decreased
Original languageEnglish
Title of host publicationNatural gas conversion : international symposium : proceedings, Oslo, August 12-17, 1990
EditorsA. Holmen, K.-J. Jens, S. Kolboe
Place of PublicationAmsterdam
PublisherElsevier
Pages235-241
ISBN (Print)0-444-88735-0
DOIs
Publication statusPublished - 1991
Eventconference; Natural Gas Conversion Symposium ; (Oslo) : 1990.08.12-17; 1990-08-12; 1990-08-17 -
Duration: 12 Aug 199017 Aug 1990

Publication series

NameStudies in Surface Science and Catalysis
Volume61
ISSN (Print)0167-2991

Conference

Conferenceconference; Natural Gas Conversion Symposium ; (Oslo) : 1990.08.12-17; 1990-08-12; 1990-08-17
Period12/08/9017/08/90
OtherNatural Gas Conversion Symposium ; (Oslo) : 1990.08.12-17

Fingerprint

Vanadium Compounds
Rhodium
Acetaldehyde
Synthesis gas
Carbon Monoxide
Methane
Isotopes
Hydrogenation
Reaction rates
Desorption
Ethanol
Carbon
Catalysts

Cite this

Koerts, T., Welters, W. J. J., Santen, van, R. A., Nonneman, L. E. Y., & Ponec, V. (1991). Promotion by vanadium compound of the elementary reaction steps in the synthesis gas reaction catalyzed by rhodium. In A. Holmen, K-J. Jens, & S. Kolboe (Eds.), Natural gas conversion : international symposium : proceedings, Oslo, August 12-17, 1990 (pp. 235-241). (Studies in Surface Science and Catalysis; Vol. 61). Amsterdam: Elsevier. https://doi.org/10.1016/S0167-2991(08)60086-5
Koerts, T. ; Welters, W.J.J. ; Santen, van, R.A. ; Nonneman, L.E.Y. ; Ponec, V. / Promotion by vanadium compound of the elementary reaction steps in the synthesis gas reaction catalyzed by rhodium. Natural gas conversion : international symposium : proceedings, Oslo, August 12-17, 1990. editor / A. Holmen ; K.-J. Jens ; S. Kolboe. Amsterdam : Elsevier, 1991. pp. 235-241 (Studies in Surface Science and Catalysis).
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abstract = "In order to understand the promoting effect of V compd. on Rh catalysts in synthesis gas conversion, changes in reaction rates of elementary steps and the surface concn. of intermediates have been monitored. V promotion enhances the rate of CO dissocn. which is the most important effect. Reactive surface carbon is stabilized by V which results in a slightly decreased reactivity in methane formation. Transient expts. using isotopes and GCMS detection show that CO insertion is not promoted by V. The hydrogenation of ethanal to ethanol is enhanced by V while the desorption rate of ethanal is decreased",
author = "T. Koerts and W.J.J. Welters and {Santen, van}, R.A. and L.E.Y. Nonneman and V. Ponec",
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Koerts, T, Welters, WJJ, Santen, van, RA, Nonneman, LEY & Ponec, V 1991, Promotion by vanadium compound of the elementary reaction steps in the synthesis gas reaction catalyzed by rhodium. in A Holmen, K-J Jens & S Kolboe (eds), Natural gas conversion : international symposium : proceedings, Oslo, August 12-17, 1990. Studies in Surface Science and Catalysis, vol. 61, Elsevier, Amsterdam, pp. 235-241, conference; Natural Gas Conversion Symposium ; (Oslo) : 1990.08.12-17; 1990-08-12; 1990-08-17, 12/08/90. https://doi.org/10.1016/S0167-2991(08)60086-5

Promotion by vanadium compound of the elementary reaction steps in the synthesis gas reaction catalyzed by rhodium. / Koerts, T.; Welters, W.J.J.; Santen, van, R.A.; Nonneman, L.E.Y.; Ponec, V.

Natural gas conversion : international symposium : proceedings, Oslo, August 12-17, 1990. ed. / A. Holmen; K.-J. Jens; S. Kolboe. Amsterdam : Elsevier, 1991. p. 235-241 (Studies in Surface Science and Catalysis; Vol. 61).

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademicpeer-review

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Koerts T, Welters WJJ, Santen, van RA, Nonneman LEY, Ponec V. Promotion by vanadium compound of the elementary reaction steps in the synthesis gas reaction catalyzed by rhodium. In Holmen A, Jens K-J, Kolboe S, editors, Natural gas conversion : international symposium : proceedings, Oslo, August 12-17, 1990. Amsterdam: Elsevier. 1991. p. 235-241. (Studies in Surface Science and Catalysis). https://doi.org/10.1016/S0167-2991(08)60086-5