Preparation, structure and photoluminescence properties of Eu2+ and Ce3+ -doped SrYSi4N7

Y.Q. Li; C.M. Fang; G. With, de; H.T.J.M. Hintzen

doi:10.1016/j.jssc.2004.07.054

Preparation, structure and photoluminescence properties of Eu2+ and Ce3+ -doped SrYSi4N7

Y.Q. Li
, C.M. Fang
, G. With, de
, H.T.J.M. Hintzen

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

Undoped and Eu2+ or Ce3+-doped SrYSi4N7 were synthesized by solid-state reaction method at 1400¿1660 °C under nitrogen/hydrogen atmosphere. The crystal structure was refined from the X-ray powder diffraction data by the Rietveld method. SrYSi4N7 and EuYSi4N7, being isotypic with the family of compounds MYbSi4N7 (M=Sr, Eu, Ba) and BaYSi4N7, crystallize with the hexagonal symmetry: space group P63mc (No. 186), Z=2, a=6.0160 (1) Å, c=9.7894 (1) Å, V=306.83(3) Å3; and a=6.0123 (1) Å, c=9.7869 (1) Å, V=306.37(1) Å3, respectively. Photoluminescence properties have been studied for Sr1−xEuxYSi4N7 (x=0¿1) and SrY1−xCexSi4N7 (x=0¿0.03) at room temperature. Eu2+-doped SrYSi4N7 shows a broad yellow emission band peaking around 548¿570 nm, while Ce3+-doped SrYSi4N7 exhibits a blue emission band with a maximum at about 450 nm. SrYSi4N7:Eu2+ can be very well excited by 390 nm radiation, which makes this material attractive as conversion phosphor for LED lighting applications.

Original language	English
Pages (from-to)	4687-4694
Number of pages	8
Journal	Journal of Solid State Chemistry
Volume	177
Issue number	12
DOIs	https://doi.org/10.1016/j.jssc.2004.07.054
Publication status	Published - 2004

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@article{d35f47b10b4a4e9fa19206bcb7730dfe,

title = "Preparation, structure and photoluminescence properties of Eu2+ and Ce3+ -doped SrYSi4N7",

abstract = "Undoped and Eu2+ or Ce3+-doped SrYSi4N7 were synthesized by solid-state reaction method at 1400¿1660 °C under nitrogen/hydrogen atmosphere. The crystal structure was refined from the X-ray powder diffraction data by the Rietveld method. SrYSi4N7 and EuYSi4N7, being isotypic with the family of compounds MYbSi4N7 (M=Sr, Eu, Ba) and BaYSi4N7, crystallize with the hexagonal symmetry: space group P63mc (No. 186), Z=2, a=6.0160 (1) {\AA}, c=9.7894 (1) {\AA}, V=306.83(3) {\AA}3; and a=6.0123 (1) {\AA}, c=9.7869 (1) {\AA}, V=306.37(1) {\AA}3, respectively. Photoluminescence properties have been studied for Sr1−xEuxYSi4N7 (x=0¿1) and SrY1−xCexSi4N7 (x=0¿0.03) at room temperature. Eu2+-doped SrYSi4N7 shows a broad yellow emission band peaking around 548¿570 nm, while Ce3+-doped SrYSi4N7 exhibits a blue emission band with a maximum at about 450 nm. SrYSi4N7:Eu2+ can be very well excited by 390 nm radiation, which makes this material attractive as conversion phosphor for LED lighting applications.",

author = "Y.Q. Li and C.M. Fang and \{With, de\}, G. and H.T.J.M. Hintzen",

year = "2004",

doi = "10.1016/j.jssc.2004.07.054",

language = "English",

volume = "177",

pages = "4687--4694",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

number = "12",

}

TY - JOUR

T1 - Preparation, structure and photoluminescence properties of Eu2+ and Ce3+ -doped SrYSi4N7

AU - Li, Y.Q.

AU - Fang, C.M.

AU - With, de, G.

AU - Hintzen, H.T.J.M.

PY - 2004

Y1 - 2004

N2 - Undoped and Eu2+ or Ce3+-doped SrYSi4N7 were synthesized by solid-state reaction method at 1400¿1660 °C under nitrogen/hydrogen atmosphere. The crystal structure was refined from the X-ray powder diffraction data by the Rietveld method. SrYSi4N7 and EuYSi4N7, being isotypic with the family of compounds MYbSi4N7 (M=Sr, Eu, Ba) and BaYSi4N7, crystallize with the hexagonal symmetry: space group P63mc (No. 186), Z=2, a=6.0160 (1) Å, c=9.7894 (1) Å, V=306.83(3) Å3; and a=6.0123 (1) Å, c=9.7869 (1) Å, V=306.37(1) Å3, respectively. Photoluminescence properties have been studied for Sr1−xEuxYSi4N7 (x=0¿1) and SrY1−xCexSi4N7 (x=0¿0.03) at room temperature. Eu2+-doped SrYSi4N7 shows a broad yellow emission band peaking around 548¿570 nm, while Ce3+-doped SrYSi4N7 exhibits a blue emission band with a maximum at about 450 nm. SrYSi4N7:Eu2+ can be very well excited by 390 nm radiation, which makes this material attractive as conversion phosphor for LED lighting applications.

AB - Undoped and Eu2+ or Ce3+-doped SrYSi4N7 were synthesized by solid-state reaction method at 1400¿1660 °C under nitrogen/hydrogen atmosphere. The crystal structure was refined from the X-ray powder diffraction data by the Rietveld method. SrYSi4N7 and EuYSi4N7, being isotypic with the family of compounds MYbSi4N7 (M=Sr, Eu, Ba) and BaYSi4N7, crystallize with the hexagonal symmetry: space group P63mc (No. 186), Z=2, a=6.0160 (1) Å, c=9.7894 (1) Å, V=306.83(3) Å3; and a=6.0123 (1) Å, c=9.7869 (1) Å, V=306.37(1) Å3, respectively. Photoluminescence properties have been studied for Sr1−xEuxYSi4N7 (x=0¿1) and SrY1−xCexSi4N7 (x=0¿0.03) at room temperature. Eu2+-doped SrYSi4N7 shows a broad yellow emission band peaking around 548¿570 nm, while Ce3+-doped SrYSi4N7 exhibits a blue emission band with a maximum at about 450 nm. SrYSi4N7:Eu2+ can be very well excited by 390 nm radiation, which makes this material attractive as conversion phosphor for LED lighting applications.

U2 - 10.1016/j.jssc.2004.07.054

DO - 10.1016/j.jssc.2004.07.054

M3 - Article

SN - 0022-4596

VL - 177

SP - 4687

EP - 4694

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 12

ER -

Preparation, structure and photoluminescence properties of Eu2+ and Ce3+ -doped SrYSi4N7

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